TY - JOUR
T1 - Evolution Mechanism and Thermal Transport Properties of Surface-Activated Bonded SiC/SiC Interfaces
AU - Zhao, Xinlong
AU - Song, Baojun
AU - Qu, Yongfeng
AU - Deng, Ningkang
AU - Yuan, Jin
AU - Hu, Wenbo
AU - Zhang, Zhaoyang
AU - Wang, Hongxing
N1 - Publisher Copyright:
© 2025 American Chemical Society
PY - 2025/11/5
Y1 - 2025/11/5
N2 - The driver control chips for high-power silicon carbide (SiC) power devices rely on silicon-based CMOS processes, which lead to parasitic effects and thermal management bottlenecks. Customisable design of nanotransition layers for SiC surface-activated bonding (SAB) has demonstrated significant application value. However, current SAB research focuses on process validation of specific material combinations and lacks understanding of the underlying principles governing surface-activated bond design. The experimental findings suggest that the sputtering-deposition time, rather than the Ar atom bombardment time, plays a pivotal role in the control of the bonding interface. In the initial stage of sputtering-deposition, the deposited layer exhibits a low density, leading to a thicker and inferior interface. As time increased, the deposited layer undergoes a gradual densification process, ultimately resulting in the formation of Fe single-crystal interfaces and the establishment of atomic-level bonding between Fe and SiC. Molecular dynamics simulations confirm the fracture mechanism at the single-crystal SiC/Fe/SiC interface, where fracture occurs within the Fe transition layer. In addition, the interfacial thermal resistance of SiC/Fe/SiC interface (4.53 m2K/GW) is lower than that of the thinner amorphous carbon SiC/a-C/SiC interface (6.74 m2K/GW). The present work reveals a universal theoretical framework for expanding the application of surface activation bonding technology in power module packaging, photonic integration, and other fields.
AB - The driver control chips for high-power silicon carbide (SiC) power devices rely on silicon-based CMOS processes, which lead to parasitic effects and thermal management bottlenecks. Customisable design of nanotransition layers for SiC surface-activated bonding (SAB) has demonstrated significant application value. However, current SAB research focuses on process validation of specific material combinations and lacks understanding of the underlying principles governing surface-activated bond design. The experimental findings suggest that the sputtering-deposition time, rather than the Ar atom bombardment time, plays a pivotal role in the control of the bonding interface. In the initial stage of sputtering-deposition, the deposited layer exhibits a low density, leading to a thicker and inferior interface. As time increased, the deposited layer undergoes a gradual densification process, ultimately resulting in the formation of Fe single-crystal interfaces and the establishment of atomic-level bonding between Fe and SiC. Molecular dynamics simulations confirm the fracture mechanism at the single-crystal SiC/Fe/SiC interface, where fracture occurs within the Fe transition layer. In addition, the interfacial thermal resistance of SiC/Fe/SiC interface (4.53 m2K/GW) is lower than that of the thinner amorphous carbon SiC/a-C/SiC interface (6.74 m2K/GW). The present work reveals a universal theoretical framework for expanding the application of surface activation bonding technology in power module packaging, photonic integration, and other fields.
KW - SiC/SiC interface
KW - molecular dynamics
KW - sputtering-deposition effect
KW - surface activated bonding
KW - thermal boundary resistance
UR - https://www.scopus.com/pages/publications/105020713931
U2 - 10.1021/acsami.5c11466
DO - 10.1021/acsami.5c11466
M3 - 文章
C2 - 41118520
AN - SCOPUS:105020713931
SN - 1944-8244
VL - 17
SP - 61396
EP - 61409
JO - ACS Applied Materials and Interfaces
JF - ACS Applied Materials and Interfaces
IS - 44
ER -