Enhancing the Surface Flashover Strength of Polystyrene in Vacuum by Secondary Electron Emission Suppression through Cross-Linking

Insulation materials with excellent dielectrics-vacuum interface breakdown strength are irreplaceable in equipment such as particle accelerators, fusion ignition, and related aerospace devices. In this article, the segment structure of a typical insulation polymer, polystyrene, has been modified by introducing divinylbenzene to form cross-linking junctures and adjust the cross-linking density. The influence of cross-linking on its electron absorb-emit feature and further on the vacuum pulsed flashover characteristics has been systematically studied. A series of broadband dielectric spectroscopy (BDS) and thermally stimulated current (TSC) experiments indicate that this cross-linking network inhibits the movement of the polar segments, leading to a drastic change in the charge-trapping behavior of dielectric surface layer materials. The trapping charge density is increased, and the trapping energy is transferred to deeper-level regions. These lead to the observed suppression of secondary electron emission (SEE) of highly cross-linked polystyrenes exposed in vacuum. And, quite sensibly, the nanosecond pulsed vacuum flashover tests show that the polystyrenes with higher cross-linking density have enhanced flashover strength. Moreover, to further investigate the relationship between the dielectric SEE behavior and its vacuum flashover process, a 2-D model is established and analyzed on the basis of the particle in the cell with the Monte Carlo collision (PIC-MCC) method.