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Enhancing plasma-sprayed LSCF cathode performance by infiltration method

  • Xi'an Jiaotong University

科研成果: 书/报告/会议事项章节会议稿件同行评审

摘要

LSCF(La0.6Sr0.4Co0.2Fe0.8O3) with a perovskite structure has been widely studied as cathode materials for intermediate solid oxide fuel cell(SOFC). It has well-known excellent electrode performance due to its high ionic and electronic conductivity. However, application of LSCF cathode is likely to be limited by the surface catalytic properties and long term stability. Sr and Co may segregate from LSCF under cathode polarization, leading to increased resistance of the cathode. Oxygen hyper- stoichiometric La2NiO4+δ with a K2NiF4 structure possesses a higher catalytic properties, ionic conductivity and stability compared to LSCF cathode. However, the electrical conductivity of the La2NiO4+δ (76 S cm-1 at 800 °C ) in the IT range are lower than 100 S/cm, which is regarded as the minimum requirement in electrical conductivity for an SOFC cathode. Taking account of both the advantages and disadvantages of the two different cathode materials, and good chemical compatibility of those two cathode materials, it is possible to prepare a composite cathode by infiltrating a thin film of La2NiO4+δ on the porous LSCF to enhance the LSCF cathode performance. Therefore, in this study, the LSCF cathode was deposited by atmospheric plasma spray. The porous LSCF cathode was infiltrated by La2NiO4+δ. The microstructure was characterized by SEM and TEM. The effect of infiltration on the polarization of LSCF cathode was investigated.

源语言英语
主期刊名ASM International - International Thermal Spray Conference and Exposition, ITSC 2015
编辑Arvind Agarwal, Yuk-Chiu Lau, Christian A. Widener, Erja Turunen, Giovanni Bolelli, Amadeu Concustell, Andre McDonald, Filofteia-Laura Toma
出版商ASM International
996-1000
页数5
ISBN(电子版)9781510811546
出版状态已出版 - 2015
活动International Thermal Spray Conference and Exposition, ITSC 2015 - Long Beach, 美国
期限: 11 5月 201514 5月 2015

出版系列

姓名Proceedings of the International Thermal Spray Conference
2

会议

会议International Thermal Spray Conference and Exposition, ITSC 2015
国家/地区美国
Long Beach
时期11/05/1514/05/15

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