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Effects of surface modification agents on the properties of MCM-41/EP nanocomposites

  • Pan Luo
  • , Shaohui Wang
  • , Man Xu
  • , Qiulin Mu
  • , Yang Xu
  • , Darong Xie
  • Xi'an Jiaotong University

科研成果: 书/报告/会议事项章节 › 会议稿件 › 同行评审

1 引用 (Scopus)

摘要

Mesoporous molecular sieve is one of the largest inorganic material systems widely applied for their huge superficial area and ordered mesoporous. Previous studies on the mesoporous molecular sieve MCM41/epoxy nanocomposite have shown that mesoporous addition evidently enhances mechanical properties. Literatures show that the interaction between the inner and outer surfaces of nanoporous and matrix is significant. In this paper, the surface modification agents KH550 and KH792 which grafted the channel wall and outer surfaces of MCM-41 were applied separately, and the in situ polymerization was used to prepare MCM-41/EP nanocomposite. Then, dynamic mechanical analysis (DMA) was performed and power frequency dielectric property was examined to investigate the storage modulus (M'), glass transition temperatures (Tg) and breakdown filed strength of the composites. DMA results show that the M' and Tg values of KH550-modified composites were all higher than that of pure EP, whereas the M' and Tg of KH792 modified composite was almost similar to that of pure EP. The electric breakdown experimental results show that the field strength of composite was higher than that of pure epoxy. Finally, a new nanocomposite system was formed for KH550-modified composite.

源语言英语
主期刊名ICPADM 2015 - 2015 IEEE 11th International Conference on the Properties and Applications of Dielectric Materials
出版商Institute of Electrical and Electronics Engineers Inc.
页856-859
页数4
ISBN(电子版)9781479989034
DOI
出版状态已出版 - 8 10月 2015
活动11th IEEE International Conference on the Properties and Applications of Dielectric Materials, ICPADM 2015 - Sydney, 澳大利亚
期限: 19 7月 2015 → 22 7月 2015

出版系列

姓名Proceedings of the IEEE International Conference on Properties and Applications of Dielectric Materials
卷2015-October

会议

会议11th IEEE International Conference on the Properties and Applications of Dielectric Materials, ICPADM 2015
国家/地区澳大利亚
市Sydney
时期19/07/15 → 22/07/15

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