Distinct reactivity of Morita-Baylis-Hillman acetates as a novel C 2 component in amine-catalyzed [2 + 2 + 2] and [2 + 4] annulations

Rongshun Chen; Silong Xu; Liyi Wang; Yuhai Tang; Zhengjie He

doi:10.1039/c3cc41419a

Distinct reactivity of Morita-Baylis-Hillman acetates as a novel C ₂ component in amine-catalyzed [2 + 2 + 2] and [2 + 4] annulations

Rongshun Chen
, Silong Xu
, Liyi Wang
, Yuhai Tang
, Zhengjie He

化学学院

Nankai University
Xi'an Jiaotong University

科研成果: 期刊稿件 › 文章 › 同行评审

30 引用（Scopus）

摘要

Amine-catalyzed [2 + 2 + 2] and [2 + 4] annulations of Morita-Baylis-Hillman (MBH) acetates with cyano activated alkenes and 1,3-azadienes have been developed to provide cyclohexanes and tetrahydropyridines. In the annulations, MBH acetates serve as a novel C ₂ component with an inactive homoallylic methyl involved in the bond formation.

源语言	英语
页（从-至）	3543-3545
页数	3
期刊	Chemical Communications
卷	49
期	34
DOI	https://doi.org/10.1039/c3cc41419a
出版状态	已出版 - 2 4月 2013

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10.1039/c3cc41419a

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abstract = "Amine-catalyzed [2 + 2 + 2] and [2 + 4] annulations of Morita-Baylis-Hillman (MBH) acetates with cyano activated alkenes and 1,3-azadienes have been developed to provide cyclohexanes and tetrahydropyridines. In the annulations, MBH acetates serve as a novel C 2 component with an inactive homoallylic methyl involved in the bond formation.",

author = "Rongshun Chen and Silong Xu and Liyi Wang and Yuhai Tang and Zhengjie He",

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T1 - Distinct reactivity of Morita-Baylis-Hillman acetates as a novel C 2 component in amine-catalyzed [2 + 2 + 2] and [2 + 4] annulations

AU - Chen, Rongshun

AU - Xu, Silong

AU - Wang, Liyi

AU - Tang, Yuhai

AU - He, Zhengjie

PY - 2013/4/2

Y1 - 2013/4/2

N2 - Amine-catalyzed [2 + 2 + 2] and [2 + 4] annulations of Morita-Baylis-Hillman (MBH) acetates with cyano activated alkenes and 1,3-azadienes have been developed to provide cyclohexanes and tetrahydropyridines. In the annulations, MBH acetates serve as a novel C 2 component with an inactive homoallylic methyl involved in the bond formation.

AB - Amine-catalyzed [2 + 2 + 2] and [2 + 4] annulations of Morita-Baylis-Hillman (MBH) acetates with cyano activated alkenes and 1,3-azadienes have been developed to provide cyclohexanes and tetrahydropyridines. In the annulations, MBH acetates serve as a novel C 2 component with an inactive homoallylic methyl involved in the bond formation.

UR - https://www.scopus.com/pages/publications/84875861738

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DO - 10.1039/c3cc41419a

M3 - 文章

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SN - 1359-7345

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JO - Chemical Communications

JF - Chemical Communications

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ER -

Distinct reactivity of Morita-Baylis-Hillman acetates as a novel C 2 component in amine-catalyzed [2 + 2 + 2] and [2 + 4] annulations

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Distinct reactivity of Morita-Baylis-Hillman acetates as a novel C ₂ component in amine-catalyzed [2 + 2 + 2] and [2 + 4] annulations