DIRECT PREPARATION OF CE0.8SM0.2O1.9 POWDERS OXIDIZED WITH H2O2 FOR LOW TEMPERATURE SOFCS APPLICATION

Jianbing Huang; Zongqiang Mao; Bin Zhu; Lizhai Yang; Ranran Peng; Ruifeng Gao

doi:10.1115/FUELCELL2005-74027

DIRECT PREPARATION OF CE_0.8SM_0.2O_1.9 POWDERS OXIDIZED WITH H₂O₂ FOR LOW TEMPERATURE SOFCS APPLICATION

Jianbing Huang
, Zongqiang Mao
, Bin Zhu
, Lizhai Yang
, Ranran Peng
, Ruifeng Gao

Tsinghua University
KTH Royal Institute of Technology

科研成果: 书/报告/会议事项章节 › 会议稿件 › 同行评审

摘要

A novel method was developed to prepare fine doped ceria (DCO) powders directly. Ceria doped with 20 mol. % of samarium (Ce_0.8Sm_0.2O_1.9, SDC) was prepared by in-situ oxidization of hydroxide precipitates with H₂O₂ in the solutions. The resultant powder desiccated at 85℃ overnight was characterized by X-ray diffraction (XRD), thermogravimetry/differential thermal analysis (TG/DTA), and transmission electron microscopy (TEM). The XRD pattern showed that the as-dried SDC powder is single phase with a cubic fluorite structure like that of pure CeO₂. An anode-supported SOFC was also fabricated based on SDC and 20wt. % (62mol. %Li₂CO₃-38 mol. %K₂CO₃) composite electrolyte, LiNiO₂ as cathode and NiO as anode, by cold pressing. Using hydrogen as the fuel and air as the oxidant, the I-V and I-P characteristics exhibit excellent performances and the maximum power densities are about 696, 469, 377 and 240 mWcm^-2 at 650, 600, 550 and 500℃, respectively.

源语言	英语
主期刊名	ASME 2005 3rd International Conference on Fuel Cell Science, Engineering and Technology, FUELCELL 2005
出版商	American Society of Mechanical Engineers (ASME)
页	295-298
页数	4
ISBN（电子版）	0791837645, 9780791837641
DOI	https://doi.org/10.1115/FUELCELL2005-74027
出版状态	已出版 - 2005
已对外发布	是
活动	ASME 2005 3rd International Conference on Fuel Cell Science, Engineering and Technology, FUELCELL 2005 - Ypsilanti, 美国期限: 23 5月 2005 → 25 5月 2005

出版系列

姓名	ASME 2005 3rd International Conference on Fuel Cell Science, Engineering and Technology, FUELCELL 2005

会议

会议	ASME 2005 3rd International Conference on Fuel Cell Science, Engineering and Technology, FUELCELL 2005
国家/地区	美国
市	Ypsilanti
时期	23/05/05 → 25/05/05

联合国可持续发展目标

此成果有助于实现下列可持续发展目标：

可持续发展目标 7 经济适用的清洁能源

访问文件

10.1115/FUELCELL2005-74027

其它文件与链接

链接到 Scopus 的出版物

引用此

Huang, J., Mao, Z., Zhu, B., Yang, L., Peng, R., & Gao, R. (2005). DIRECT PREPARATION OF CE_0.8SM_0.2O_1.9 POWDERS OXIDIZED WITH H₂O₂ FOR LOW TEMPERATURE SOFCS APPLICATION. 在 ASME 2005 3rd International Conference on Fuel Cell Science, Engineering and Technology, FUELCELL 2005 (页码 295-298). (ASME 2005 3rd International Conference on Fuel Cell Science, Engineering and Technology, FUELCELL 2005). American Society of Mechanical Engineers (ASME). https://doi.org/10.1115/FUELCELL2005-74027

Huang, Jianbing ; Mao, Zongqiang ; Zhu, Bin 等. / DIRECT PREPARATION OF CE_0.8SM_0.2O_1.9 POWDERS OXIDIZED WITH H₂O₂ FOR LOW TEMPERATURE SOFCS APPLICATION. ASME 2005 3rd International Conference on Fuel Cell Science, Engineering and Technology, FUELCELL 2005. American Society of Mechanical Engineers (ASME), 2005. 页码 295-298 (ASME 2005 3rd International Conference on Fuel Cell Science, Engineering and Technology, FUELCELL 2005).

@inproceedings{3028353eb8234f62b52c439abb45e8d8,

title = "DIRECT PREPARATION OF CE0.8SM0.2O1.9 POWDERS OXIDIZED WITH H2O2 FOR LOW TEMPERATURE SOFCS APPLICATION",

abstract = "A novel method was developed to prepare fine doped ceria (DCO) powders directly. Ceria doped with 20 mol. \% of samarium (Ce0.8Sm0.2O1.9, SDC) was prepared by in-situ oxidization of hydroxide precipitates with H2O2 in the solutions. The resultant powder desiccated at 85℃ overnight was characterized by X-ray diffraction (XRD), thermogravimetry/differential thermal analysis (TG/DTA), and transmission electron microscopy (TEM). The XRD pattern showed that the as-dried SDC powder is single phase with a cubic fluorite structure like that of pure CeO2. An anode-supported SOFC was also fabricated based on SDC and 20wt. \% (62mol. \%Li2CO3-38 mol. \%K2CO3) composite electrolyte, LiNiO2 as cathode and NiO as anode, by cold pressing. Using hydrogen as the fuel and air as the oxidant, the I-V and I-P characteristics exhibit excellent performances and the maximum power densities are about 696, 469, 377 and 240 mWcm-2 at 650, 600, 550 and 500℃, respectively.",

keywords = "HO, composite electrolyte, low temperature solid oxide fuel cells (LTSOFCs), oxidization, samarium doped ceria (SDC)",

author = "Jianbing Huang and Zongqiang Mao and Bin Zhu and Lizhai Yang and Ranran Peng and Ruifeng Gao",

note = "Publisher Copyright: Copyright {\textcopyright} 2005 by ASME.; ASME 2005 3rd International Conference on Fuel Cell Science, Engineering and Technology, FUELCELL 2005 ; Conference date: 23-05-2005 Through 25-05-2005",

year = "2005",

doi = "10.1115/FUELCELL2005-74027",

language = "英语",

series = "ASME 2005 3rd International Conference on Fuel Cell Science, Engineering and Technology, FUELCELL 2005",

publisher = "American Society of Mechanical Engineers (ASME)",

pages = "295--298",

booktitle = "ASME 2005 3rd International Conference on Fuel Cell Science, Engineering and Technology, FUELCELL 2005",

}

Huang, J, Mao, Z, Zhu, B, Yang, L, Peng, R & Gao, R 2005, DIRECT PREPARATION OF CE_0.8SM_0.2O_1.9 POWDERS OXIDIZED WITH H₂O₂ FOR LOW TEMPERATURE SOFCS APPLICATION. 在 ASME 2005 3rd International Conference on Fuel Cell Science, Engineering and Technology, FUELCELL 2005. ASME 2005 3rd International Conference on Fuel Cell Science, Engineering and Technology, FUELCELL 2005, American Society of Mechanical Engineers (ASME), 页码 295-298, ASME 2005 3rd International Conference on Fuel Cell Science, Engineering and Technology, FUELCELL 2005, Ypsilanti, 美国, 23/05/05. https://doi.org/10.1115/FUELCELL2005-74027

DIRECT PREPARATION OF CE_0.8SM_0.2O_1.9 POWDERS OXIDIZED WITH H₂O₂ FOR LOW TEMPERATURE SOFCS APPLICATION. / Huang, Jianbing; Mao, Zongqiang; Zhu, Bin 等.
ASME 2005 3rd International Conference on Fuel Cell Science, Engineering and Technology, FUELCELL 2005. American Society of Mechanical Engineers (ASME), 2005. 页码 295-298 (ASME 2005 3rd International Conference on Fuel Cell Science, Engineering and Technology, FUELCELL 2005).

科研成果: 书/报告/会议事项章节 › 会议稿件 › 同行评审

TY - GEN

T1 - DIRECT PREPARATION OF CE0.8SM0.2O1.9 POWDERS OXIDIZED WITH H2O2 FOR LOW TEMPERATURE SOFCS APPLICATION

AU - Huang, Jianbing

AU - Mao, Zongqiang

AU - Zhu, Bin

AU - Yang, Lizhai

AU - Peng, Ranran

AU - Gao, Ruifeng

PY - 2005

Y1 - 2005

N2 - A novel method was developed to prepare fine doped ceria (DCO) powders directly. Ceria doped with 20 mol. % of samarium (Ce0.8Sm0.2O1.9, SDC) was prepared by in-situ oxidization of hydroxide precipitates with H2O2 in the solutions. The resultant powder desiccated at 85℃ overnight was characterized by X-ray diffraction (XRD), thermogravimetry/differential thermal analysis (TG/DTA), and transmission electron microscopy (TEM). The XRD pattern showed that the as-dried SDC powder is single phase with a cubic fluorite structure like that of pure CeO2. An anode-supported SOFC was also fabricated based on SDC and 20wt. % (62mol. %Li2CO3-38 mol. %K2CO3) composite electrolyte, LiNiO2 as cathode and NiO as anode, by cold pressing. Using hydrogen as the fuel and air as the oxidant, the I-V and I-P characteristics exhibit excellent performances and the maximum power densities are about 696, 469, 377 and 240 mWcm-2 at 650, 600, 550 and 500℃, respectively.

AB - A novel method was developed to prepare fine doped ceria (DCO) powders directly. Ceria doped with 20 mol. % of samarium (Ce0.8Sm0.2O1.9, SDC) was prepared by in-situ oxidization of hydroxide precipitates with H2O2 in the solutions. The resultant powder desiccated at 85℃ overnight was characterized by X-ray diffraction (XRD), thermogravimetry/differential thermal analysis (TG/DTA), and transmission electron microscopy (TEM). The XRD pattern showed that the as-dried SDC powder is single phase with a cubic fluorite structure like that of pure CeO2. An anode-supported SOFC was also fabricated based on SDC and 20wt. % (62mol. %Li2CO3-38 mol. %K2CO3) composite electrolyte, LiNiO2 as cathode and NiO as anode, by cold pressing. Using hydrogen as the fuel and air as the oxidant, the I-V and I-P characteristics exhibit excellent performances and the maximum power densities are about 696, 469, 377 and 240 mWcm-2 at 650, 600, 550 and 500℃, respectively.

KW - HO

KW - composite electrolyte

KW - low temperature solid oxide fuel cells (LTSOFCs)

KW - oxidization

KW - samarium doped ceria (SDC)

UR - https://www.scopus.com/pages/publications/85148099609

U2 - 10.1115/FUELCELL2005-74027

DO - 10.1115/FUELCELL2005-74027

M3 - 会议稿件

AN - SCOPUS:85148099609

T3 - ASME 2005 3rd International Conference on Fuel Cell Science, Engineering and Technology, FUELCELL 2005

SP - 295

EP - 298

BT - ASME 2005 3rd International Conference on Fuel Cell Science, Engineering and Technology, FUELCELL 2005

PB - American Society of Mechanical Engineers (ASME)

T2 - ASME 2005 3rd International Conference on Fuel Cell Science, Engineering and Technology, FUELCELL 2005

Y2 - 23 May 2005 through 25 May 2005

ER -

Huang J, Mao Z, Zhu B, Yang L, Peng R, Gao R. DIRECT PREPARATION OF CE_0.8SM_0.2O_1.9 POWDERS OXIDIZED WITH H₂O₂ FOR LOW TEMPERATURE SOFCS APPLICATION. 在 ASME 2005 3rd International Conference on Fuel Cell Science, Engineering and Technology, FUELCELL 2005. American Society of Mechanical Engineers (ASME). 2005. 页码 295-298. (ASME 2005 3rd International Conference on Fuel Cell Science, Engineering and Technology, FUELCELL 2005). doi: 10.1115/FUELCELL2005-74027