D˙–A radicals fabricated from polychlorinated trityl and pyridinium featuring a SOMO–LUMO electronic transition

Jingwen Li; Ziqi Zhang; Zenghui Li; Jing Wang; Changyuan Xu; Jie Xiong; Ling Yue; Bin Rao

doi:10.1039/d6cc00928j

D˙–A radicals fabricated from polychlorinated trityl and pyridinium featuring a SOMO–LUMO electronic transition

Jingwen Li
, Ziqi Zhang
, Zenghui Li
, Jing Wang
, Changyuan Xu
, Jie Xiong
, Ling Yue
, Bin Rao

化学学院

Xi'an Jiaotong University

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

D˙–A radicals 2a–2c were developed by combining polychlorinated trityl as a donor with pyridinium as an acceptor. The electron-deficient nature of the pyridinium unit significantly lowers the LUMO energy, thereby enabling SOMO–LUMO (α-type) electronic transitions, in contrast to conventional luminescent radicals that predominantly exhibit HOMO–SUMO (β-type) transitions.

源语言	英语
页（从-至）	7558-7562
页数	5
期刊	Chemical Communications
卷	62
期	29
DOI	https://doi.org/10.1039/d6cc00928j
出版状态	已出版 - 16 4月 2026

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10.1039/d6cc00928j

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title = "D˙–A radicals fabricated from polychlorinated trityl and pyridinium featuring a SOMO–LUMO electronic transition",

abstract = "D˙–A radicals 2a–2c were developed by combining polychlorinated trityl as a donor with pyridinium as an acceptor. The electron-deficient nature of the pyridinium unit significantly lowers the LUMO energy, thereby enabling SOMO–LUMO (α-type) electronic transitions, in contrast to conventional luminescent radicals that predominantly exhibit HOMO–SUMO (β-type) transitions.",

author = "Jingwen Li and Ziqi Zhang and Zenghui Li and Jing Wang and Changyuan Xu and Jie Xiong and Ling Yue and Bin Rao",

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T1 - D˙–A radicals fabricated from polychlorinated trityl and pyridinium featuring a SOMO–LUMO electronic transition

AU - Li, Jingwen

AU - Zhang, Ziqi

AU - Li, Zenghui

AU - Wang, Jing

AU - Xu, Changyuan

AU - Xiong, Jie

AU - Yue, Ling

AU - Rao, Bin

PY - 2026/4/16

Y1 - 2026/4/16

N2 - D˙–A radicals 2a–2c were developed by combining polychlorinated trityl as a donor with pyridinium as an acceptor. The electron-deficient nature of the pyridinium unit significantly lowers the LUMO energy, thereby enabling SOMO–LUMO (α-type) electronic transitions, in contrast to conventional luminescent radicals that predominantly exhibit HOMO–SUMO (β-type) transitions.

AB - D˙–A radicals 2a–2c were developed by combining polychlorinated trityl as a donor with pyridinium as an acceptor. The electron-deficient nature of the pyridinium unit significantly lowers the LUMO energy, thereby enabling SOMO–LUMO (α-type) electronic transitions, in contrast to conventional luminescent radicals that predominantly exhibit HOMO–SUMO (β-type) transitions.

UR - https://www.scopus.com/pages/publications/105034348862

U2 - 10.1039/d6cc00928j

DO - 10.1039/d6cc00928j

M3 - 文章

C2 - 41906908

AN - SCOPUS:105034348862

SN - 1359-7345

VL - 62

SP - 7558

EP - 7562

JO - Chemical Communications

JF - Chemical Communications

IS - 29

ER -

D˙–A radicals fabricated from polychlorinated trityl and pyridinium featuring a SOMO–LUMO electronic transition

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