Cr-methanol fuel cell for efficient Cr(VI) removal and high power production

Qing Yun Chen; Rong Fu; Xiao Wen Fang; Wen Fang Cai; Yun Hai Wang; Shao An Cheng

doi:10.1016/j.apenergy.2014.10.053

Cr-methanol fuel cell for efficient Cr(VI) removal and high power production

Qing Yun Chen
, Rong Fu
, Xiao Wen Fang
, Wen Fang Cai
, Yun Hai Wang
, Shao An Cheng

能源与动力工程学院

Xi'an Jiaotong University
Zhejiang University

科研成果: 期刊稿件 › 文章 › 同行评审

10 引用（Scopus）

摘要

A novel Cr-methanol fuel cell was designed to remove Cr(VI) with simultaneous electricity production. In this design, methanol was oxidized on anode, while Cr(VI) was reduced on cathode. With 2molL^-1 sodium hydroxide as anolyte and 0.1molL^-1 sodium sulfate as catholyte, the power density output of as high as 903Wm^-2 with external resistance of 15Ω at 45°C could be obtained. More than 91% Cr(VI) could be reduced in one single cycle of around 400min. What is more, the presented electrochemical cell can steadily run in wide temperature ranges from -14°C to 45°C. Our results also demonstrated that the proposed Cr-methanol fuel cell had potential application for Cr(VI) removal with simultaneous electricity production.

源语言	英语
页（从-至）	31-35
页数	5
期刊	Applied Energy
卷	138
DOI	https://doi.org/10.1016/j.apenergy.2014.10.053
出版状态	已出版 - 5 1月 2015

联合国可持续发展目标

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可持续发展目标 7 经济适用的清洁能源

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10.1016/j.apenergy.2014.10.053

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@article{7617847287374e0fa2ba134b312cb344,

title = "Cr-methanol fuel cell for efficient Cr(VI) removal and high power production",

abstract = "A novel Cr-methanol fuel cell was designed to remove Cr(VI) with simultaneous electricity production. In this design, methanol was oxidized on anode, while Cr(VI) was reduced on cathode. With 2molL-1 sodium hydroxide as anolyte and 0.1molL-1 sodium sulfate as catholyte, the power density output of as high as 903Wm-2 with external resistance of 15Ω at 45°C could be obtained. More than 91\% Cr(VI) could be reduced in one single cycle of around 400min. What is more, the presented electrochemical cell can steadily run in wide temperature ranges from -14°C to 45°C. Our results also demonstrated that the proposed Cr-methanol fuel cell had potential application for Cr(VI) removal with simultaneous electricity production.",

keywords = "Chromium, Electricity, Electrochemical, Methanol, Wastewater",

author = "Chen, \{Qing Yun\} and Rong Fu and Fang, \{Xiao Wen\} and Cai, \{Wen Fang\} and Wang, \{Yun Hai\} and Cheng, \{Shao An\}",

note = "Publisher Copyright: {\textcopyright} 2014 Elsevier Ltd.",

year = "2015",

month = jan,

day = "5",

doi = "10.1016/j.apenergy.2014.10.053",

language = "英语",

volume = "138",

pages = "31--35",

journal = "Applied Energy",

issn = "0306-2619",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Cr-methanol fuel cell for efficient Cr(VI) removal and high power production

AU - Chen, Qing Yun

AU - Fu, Rong

AU - Fang, Xiao Wen

AU - Cai, Wen Fang

AU - Wang, Yun Hai

AU - Cheng, Shao An

PY - 2015/1/5

Y1 - 2015/1/5

N2 - A novel Cr-methanol fuel cell was designed to remove Cr(VI) with simultaneous electricity production. In this design, methanol was oxidized on anode, while Cr(VI) was reduced on cathode. With 2molL-1 sodium hydroxide as anolyte and 0.1molL-1 sodium sulfate as catholyte, the power density output of as high as 903Wm-2 with external resistance of 15Ω at 45°C could be obtained. More than 91% Cr(VI) could be reduced in one single cycle of around 400min. What is more, the presented electrochemical cell can steadily run in wide temperature ranges from -14°C to 45°C. Our results also demonstrated that the proposed Cr-methanol fuel cell had potential application for Cr(VI) removal with simultaneous electricity production.

AB - A novel Cr-methanol fuel cell was designed to remove Cr(VI) with simultaneous electricity production. In this design, methanol was oxidized on anode, while Cr(VI) was reduced on cathode. With 2molL-1 sodium hydroxide as anolyte and 0.1molL-1 sodium sulfate as catholyte, the power density output of as high as 903Wm-2 with external resistance of 15Ω at 45°C could be obtained. More than 91% Cr(VI) could be reduced in one single cycle of around 400min. What is more, the presented electrochemical cell can steadily run in wide temperature ranges from -14°C to 45°C. Our results also demonstrated that the proposed Cr-methanol fuel cell had potential application for Cr(VI) removal with simultaneous electricity production.

KW - Chromium

KW - Electricity

KW - Electrochemical

KW - Methanol

KW - Wastewater

UR - https://www.scopus.com/pages/publications/84909956884

U2 - 10.1016/j.apenergy.2014.10.053

DO - 10.1016/j.apenergy.2014.10.053

M3 - 文章

AN - SCOPUS:84909956884

SN - 0306-2619

VL - 138

SP - 31

EP - 35

JO - Applied Energy

JF - Applied Energy

ER -

Cr-methanol fuel cell for efficient Cr(VI) removal and high power production

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