Copper-mediated trifluoromethylation using phenyl trifluoromethyl sulfoxide

Xinjin Li; Jingwei Zhao; Liang Zhang; Mingyou Hu; Limin Wang; Jinbo Hu

doi:10.1021/ol5034018

Copper-mediated trifluoromethylation using phenyl trifluoromethyl sulfoxide

Xinjin Li
, Jingwei Zhao
, Liang Zhang
, Mingyou Hu
, Limin Wang
, Jinbo Hu

科研成果: 期刊稿件 › 文章 › 同行评审

76 引用（Scopus）

摘要

A new method for the generation of trifluoromethylcopper ("CuCF₃") species from readily available phenyl trifluoromethyl sulfoxide has been developed. The "CuCF₃" reagent can be applied in efficient trifluoromethylations of aryl iodides and activated aryl bromides in the absence of additional ligands. Furthermore, the "CuCF₃" species can also undergo oxidative cross-coupling with terminal alkynes and arylboronic acids.

源语言	英语
页（从-至）	298-301
页数	4
期刊	Organic Letters
卷	17
期	2
DOI	https://doi.org/10.1021/ol5034018
出版状态	已出版 - 16 1月 2015
已对外发布	是

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10.1021/ol5034018

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abstract = "A new method for the generation of trifluoromethylcopper ({"}CuCF3{"}) species from readily available phenyl trifluoromethyl sulfoxide has been developed. The {"}CuCF3{"} reagent can be applied in efficient trifluoromethylations of aryl iodides and activated aryl bromides in the absence of additional ligands. Furthermore, the {"}CuCF3{"} species can also undergo oxidative cross-coupling with terminal alkynes and arylboronic acids.",

author = "Xinjin Li and Jingwei Zhao and Liang Zhang and Mingyou Hu and Limin Wang and Jinbo Hu",

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AU - Li, Xinjin

AU - Zhao, Jingwei

AU - Zhang, Liang

AU - Hu, Mingyou

AU - Wang, Limin

AU - Hu, Jinbo

PY - 2015/1/16

Y1 - 2015/1/16

N2 - A new method for the generation of trifluoromethylcopper ("CuCF3") species from readily available phenyl trifluoromethyl sulfoxide has been developed. The "CuCF3" reagent can be applied in efficient trifluoromethylations of aryl iodides and activated aryl bromides in the absence of additional ligands. Furthermore, the "CuCF3" species can also undergo oxidative cross-coupling with terminal alkynes and arylboronic acids.

AB - A new method for the generation of trifluoromethylcopper ("CuCF3") species from readily available phenyl trifluoromethyl sulfoxide has been developed. The "CuCF3" reagent can be applied in efficient trifluoromethylations of aryl iodides and activated aryl bromides in the absence of additional ligands. Furthermore, the "CuCF3" species can also undergo oxidative cross-coupling with terminal alkynes and arylboronic acids.

UR - https://www.scopus.com/pages/publications/84921280886

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DO - 10.1021/ol5034018

M3 - 文章

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AN - SCOPUS:84921280886

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EP - 301

JO - Organic Letters

JF - Organic Letters

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ER -

Copper-mediated trifluoromethylation using phenyl trifluoromethyl sulfoxide

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