Copper-mediated trifluoromethylation of propiolic acids: Facile synthesis of α-trifluoromethyl ketones

Zhengbiao He; Rui Zhang; Mingyou Hu; Lingchun Li; Chuanfa Ni; Jinbo Hu

doi:10.1039/c3sc51613j

Copper-mediated trifluoromethylation of propiolic acids: Facile synthesis of α-trifluoromethyl ketones

Zhengbiao He
, Rui Zhang
, Mingyou Hu
, Lingchun Li
, Chuanfa Ni
, Jinbo Hu

CAS - Shanghai Institute of Organic Chemistry

科研成果: 期刊稿件 › 文章 › 同行评审

100 引用（Scopus）

摘要

Copper-mediated decarboxylative trifluoromethylation provides a new protocol for the efficient preparation of α-trifluoromethyl ketones from propiolic acids. It was found that water is involved as a reactant in the reaction, which is significantly different from the previously reported decarboxylative fluoroalkylation reactions.

源语言	英语
页（从-至）	3478-3483
页数	6
期刊	Chemical Science
卷	4
期	9
DOI	https://doi.org/10.1039/c3sc51613j
出版状态	已出版 - 29 7月 2013
已对外发布	是

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AU - Li, Lingchun

AU - Ni, Chuanfa

AU - Hu, Jinbo

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AB - Copper-mediated decarboxylative trifluoromethylation provides a new protocol for the efficient preparation of α-trifluoromethyl ketones from propiolic acids. It was found that water is involved as a reactant in the reaction, which is significantly different from the previously reported decarboxylative fluoroalkylation reactions.

UR - https://www.scopus.com/pages/publications/84886821536

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Copper-mediated trifluoromethylation of propiolic acids: Facile synthesis of α-trifluoromethyl ketones

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