Copper-catalyzed oxidative ipso-annulation of activated alkynes with silanes: An approach to 3-silyl azaspiro[4,5]trienones

A novel strategy of silylation and dearomatization of activated alkynes with silanes to synthesize azaspiro[4,5]trienones is developed, which could be facilely achieved through a tandem difunctionalization of alkyne, dearomatization, and oxidation and provided a facile approach to produce useful 3-silyl azaspiro[4,5]trienones in an efficient manner.