Copper-catalyzed alkylarylation of vinylarenes with cycloalkylsilyl peroxides and boronic acids

Shuo Yang; Pin Gao; Meng Ting Suo; Shu Xin Gao; Xin Hua Duan; Li Na Guo

doi:10.1039/d0cc04439c

Copper-catalyzed alkylarylation of vinylarenes with cycloalkylsilyl peroxides and boronic acids

Shuo Yang
, Pin Gao
, Meng Ting Suo
, Shu Xin Gao
, Xin Hua Duan
, Li Na Guo

化学学院

Xi'an Jiaotong University
Lanzhou University

科研成果: 期刊稿件 › 文章 › 同行评审

33 引用（Scopus）

摘要

A mild copper-catalyzed alkylarylation of vinylarenes with cycloalkylsilyl peroxides and boronic acids is described. This three-component protocol provides a straightforward approach to the remote keto-functionalized 1,1-diarylmethane derivatives. A radical pathway initiated by C-C bond cleavage is proposed for this tandem reaction.

源语言	英语
页（从-至）	10714-10717
页数	4
期刊	Chemical Communications
卷	56
期	73
DOI	https://doi.org/10.1039/d0cc04439c
出版状态	已出版 - 18 9月 2020

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10.1039/d0cc04439c

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abstract = "A mild copper-catalyzed alkylarylation of vinylarenes with cycloalkylsilyl peroxides and boronic acids is described. This three-component protocol provides a straightforward approach to the remote keto-functionalized 1,1-diarylmethane derivatives. A radical pathway initiated by C-C bond cleavage is proposed for this tandem reaction.",

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AU - Yang, Shuo

AU - Gao, Pin

AU - Suo, Meng Ting

AU - Gao, Shu Xin

AU - Duan, Xin Hua

AU - Guo, Li Na

PY - 2020/9/18

Y1 - 2020/9/18

N2 - A mild copper-catalyzed alkylarylation of vinylarenes with cycloalkylsilyl peroxides and boronic acids is described. This three-component protocol provides a straightforward approach to the remote keto-functionalized 1,1-diarylmethane derivatives. A radical pathway initiated by C-C bond cleavage is proposed for this tandem reaction.

AB - A mild copper-catalyzed alkylarylation of vinylarenes with cycloalkylsilyl peroxides and boronic acids is described. This three-component protocol provides a straightforward approach to the remote keto-functionalized 1,1-diarylmethane derivatives. A radical pathway initiated by C-C bond cleavage is proposed for this tandem reaction.

UR - https://www.scopus.com/pages/publications/85091126316

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Copper-catalyzed alkylarylation of vinylarenes with cycloalkylsilyl peroxides and boronic acids

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