Controlled synthesis of fully π-conjugated donor-acceptor block copolymers using a Ni(II) diimine catalyst

Colin R. Bridges; Han Yan; Adam A. Pollit; Dwight S. Seferos

doi:10.1021/mz500314p

Controlled synthesis of fully π-conjugated donor-acceptor block copolymers using a Ni(II) diimine catalyst

Colin R. Bridges
, Han Yan
, Adam A. Pollit
, Dwight S. Seferos

University of Toronto

科研成果: 期刊稿件 › 文章 › 同行评审

75 引用（Scopus）

摘要

We use a Ni(II) diimine catalyst to prepare the first examples of the controlled synthesis of electron-rich/electron-deficient all-conjugated diblock copolymers. These catalysts are able to control polymerizations of both electron-rich and electron-deficient monomers, which we attribute to strong association to both monomer types. Block copolymers are prepared by controlled chain extension, and their structure is verified by gel permeation chromatography, ¹H NMR, electrochemistry, calorimetry, and atomic force microscopy.

源语言	英语
页（从-至）	671-674
页数	4
期刊	ACS Macro Letters
卷	3
期	7
DOI	https://doi.org/10.1021/mz500314p
出版状态	已出版 - 15 7月 2014
已对外发布	是

访问文件

10.1021/mz500314p

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{c8e4a7f74fda46eeac728c0722ff3def,

title = "Controlled synthesis of fully π-conjugated donor-acceptor block copolymers using a Ni(II) diimine catalyst",

abstract = "We use a Ni(II) diimine catalyst to prepare the first examples of the controlled synthesis of electron-rich/electron-deficient all-conjugated diblock copolymers. These catalysts are able to control polymerizations of both electron-rich and electron-deficient monomers, which we attribute to strong association to both monomer types. Block copolymers are prepared by controlled chain extension, and their structure is verified by gel permeation chromatography, 1H NMR, electrochemistry, calorimetry, and atomic force microscopy.",

author = "Bridges, \{Colin R.\} and Han Yan and Pollit, \{Adam A.\} and Seferos, \{Dwight S.\}",

year = "2014",

month = jul,

day = "15",

doi = "10.1021/mz500314p",

language = "英语",

volume = "3",

pages = "671--674",

journal = "ACS Macro Letters",

issn = "2161-1653",

publisher = "American Chemical Society",

number = "7",

}

TY - JOUR

T1 - Controlled synthesis of fully π-conjugated donor-acceptor block copolymers using a Ni(II) diimine catalyst

AU - Bridges, Colin R.

AU - Yan, Han

AU - Pollit, Adam A.

AU - Seferos, Dwight S.

PY - 2014/7/15

Y1 - 2014/7/15

N2 - We use a Ni(II) diimine catalyst to prepare the first examples of the controlled synthesis of electron-rich/electron-deficient all-conjugated diblock copolymers. These catalysts are able to control polymerizations of both electron-rich and electron-deficient monomers, which we attribute to strong association to both monomer types. Block copolymers are prepared by controlled chain extension, and their structure is verified by gel permeation chromatography, 1H NMR, electrochemistry, calorimetry, and atomic force microscopy.

AB - We use a Ni(II) diimine catalyst to prepare the first examples of the controlled synthesis of electron-rich/electron-deficient all-conjugated diblock copolymers. These catalysts are able to control polymerizations of both electron-rich and electron-deficient monomers, which we attribute to strong association to both monomer types. Block copolymers are prepared by controlled chain extension, and their structure is verified by gel permeation chromatography, 1H NMR, electrochemistry, calorimetry, and atomic force microscopy.

UR - https://www.scopus.com/pages/publications/84904408816

U2 - 10.1021/mz500314p

DO - 10.1021/mz500314p

M3 - 文章

AN - SCOPUS:84904408816

SN - 2161-1653

VL - 3

SP - 671

EP - 674

JO - ACS Macro Letters

JF - ACS Macro Letters

IS - 7

ER -

Controlled synthesis of fully π-conjugated donor-acceptor block copolymers using a Ni(II) diimine catalyst

摘要

访问文件

其它文件与链接

学术指纹

引用此