Constructing hollow silkworm structure in MnOx–TiO2 catalysts for improving the performance in selective catalytic reduction of NO by NH3

Chong Xie; Shenghui Yang; Jian Wen Shi; Chunming Niu

doi:10.1007/s11144-019-01669-8

Constructing hollow silkworm structure in MnO_x–TiO₂ catalysts for improving the performance in selective catalytic reduction of NO by NH₃

Chong Xie
, Shenghui Yang
, Jian Wen Shi
, Chunming Niu

电气工程学院

Xi'an University of Technology
Xi'an Jiaotong University

科研成果: 期刊稿件 › 文章 › 同行评审

7 引用（Scopus）

摘要

A novel MnO_x–TiO₂ catalyst with hollow silkworm structure was synthesized successfully via an ethanol-thermal strategy by using activated carbon fiber felt as template for the first time. The silkworm-like MnO_x–TiO₂ catalyst (MnTi) exhibited higher NO_x conversion in the whole experimental temperature region (90–330 °C) under a high space velocity of 36,000 h⁻¹ in comparison with the common MnO_x–TiO₂ catalyst without hollow silkworm structure (MnTi-B). The excellent catalytic performance of MnTi can be attributed to its high specific surface area, large content of active surface oxygen species (O_S), and more surface acid sites. In addition, the MnTi catalyst also exhibited excellent resistance to water or SO₂ poisoning.

源语言	英语
页（从-至）	681-693
页数	13
期刊	Reaction Kinetics, Mechanisms and Catalysis
卷	128
期	2
DOI	https://doi.org/10.1007/s11144-019-01669-8
出版状态	已出版 - 1 12月 2019

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10.1007/s11144-019-01669-8

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title = "Constructing hollow silkworm structure in MnOx–TiO2 catalysts for improving the performance in selective catalytic reduction of NO by NH3",

abstract = "A novel MnOx–TiO2 catalyst with hollow silkworm structure was synthesized successfully via an ethanol-thermal strategy by using activated carbon fiber felt as template for the first time. The silkworm-like MnOx–TiO2 catalyst (MnTi) exhibited higher NOx conversion in the whole experimental temperature region (90–330 °C) under a high space velocity of 36,000 h−1 in comparison with the common MnOx–TiO2 catalyst without hollow silkworm structure (MnTi-B). The excellent catalytic performance of MnTi can be attributed to its high specific surface area, large content of active surface oxygen species (OS), and more surface acid sites. In addition, the MnTi catalyst also exhibited excellent resistance to water or SO2 poisoning.",

keywords = "Activated carbon nanofiber, Hollow structure, MnO–TiO, Selective catalytic reduction, Template",

author = "Chong Xie and Shenghui Yang and Shi, \{Jian Wen\} and Chunming Niu",

note = "Publisher Copyright: {\textcopyright} 2019, Akad{\'e}miai Kiad{\'o}, Budapest, Hungary.",

year = "2019",

month = dec,

day = "1",

doi = "10.1007/s11144-019-01669-8",

language = "英语",

volume = "128",

pages = "681--693",

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publisher = "Springer Science and Business Media B.V.",

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T1 - Constructing hollow silkworm structure in MnOx–TiO2 catalysts for improving the performance in selective catalytic reduction of NO by NH3

AU - Xie, Chong

AU - Yang, Shenghui

AU - Shi, Jian Wen

AU - Niu, Chunming

PY - 2019/12/1

Y1 - 2019/12/1

N2 - A novel MnOx–TiO2 catalyst with hollow silkworm structure was synthesized successfully via an ethanol-thermal strategy by using activated carbon fiber felt as template for the first time. The silkworm-like MnOx–TiO2 catalyst (MnTi) exhibited higher NOx conversion in the whole experimental temperature region (90–330 °C) under a high space velocity of 36,000 h−1 in comparison with the common MnOx–TiO2 catalyst without hollow silkworm structure (MnTi-B). The excellent catalytic performance of MnTi can be attributed to its high specific surface area, large content of active surface oxygen species (OS), and more surface acid sites. In addition, the MnTi catalyst also exhibited excellent resistance to water or SO2 poisoning.

AB - A novel MnOx–TiO2 catalyst with hollow silkworm structure was synthesized successfully via an ethanol-thermal strategy by using activated carbon fiber felt as template for the first time. The silkworm-like MnOx–TiO2 catalyst (MnTi) exhibited higher NOx conversion in the whole experimental temperature region (90–330 °C) under a high space velocity of 36,000 h−1 in comparison with the common MnOx–TiO2 catalyst without hollow silkworm structure (MnTi-B). The excellent catalytic performance of MnTi can be attributed to its high specific surface area, large content of active surface oxygen species (OS), and more surface acid sites. In addition, the MnTi catalyst also exhibited excellent resistance to water or SO2 poisoning.

KW - Activated carbon nanofiber

KW - Hollow structure

KW - MnO–TiO

KW - Selective catalytic reduction

KW - Template

UR - https://www.scopus.com/pages/publications/85073801635

U2 - 10.1007/s11144-019-01669-8

DO - 10.1007/s11144-019-01669-8

M3 - 文章

AN - SCOPUS:85073801635

SN - 1878-5190

VL - 128

SP - 681

EP - 693

JO - Reaction Kinetics, Mechanisms and Catalysis

JF - Reaction Kinetics, Mechanisms and Catalysis

IS - 2

ER -

Constructing hollow silkworm structure in MnOx–TiO2 catalysts for improving the performance in selective catalytic reduction of NO by NH3

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Constructing hollow silkworm structure in MnO_x–TiO₂ catalysts for improving the performance in selective catalytic reduction of NO by NH₃