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Comparison of black carbon, primary and secondary brown carbon light absorption and direct solar absorption at the foothill and summit of Mt. Hua, China

  • Chong Shu Zhu
  • , Yao Qu
  • , Wen Ting Dai
  • , Xiao Li Su
  • , Jia Mao Zhou
  • , Nan Wang
  • , Jing Qu
  • , Jun Ji Cao
  • CAS - Institute of Earth Environment
  • Guanzhong Plain Ecological Environment Change and Comprehensive Treatment National Observation and Research Station
  • Xi'an Institute for Innovative Earth Environment Research
  • Meteorological Bureau of Xi'an City

科研成果: 期刊稿件文章同行评审

11 引用 (Scopus)

摘要

Atmospheric black carbon (BC), primary and secondary brown carbon (BrCpri and BrCsec) are the light-absorbing carbonaceous aerosol components. The vertical changes in the BC and BrC distributions are not generally known. Here, we presented a study of the spectral light absorption properties, direct solar absorption, and potential source areas of BC and BrC at the foothill (375 m a.s.l.) and summit (2060 m a.s.l.) of Mt. Hua, China. More than tripled BC and BrC light absorption coefficient were observed at the foothill compared to the summit. The dominant carbonaceous light-absorbing was attributed to BC with the percentages of 77 % (foothill) and 79 % (summit), respectively. The light absorption coefficient and direct solar absorption of BrCpri were much higher than those of BrCsec at foothill, especially in winter. The enhancing contributions of BrCsec light absorption coefficient and direct solar absorption were observed with high RH and visibility at the summit. The light absorption properties of BC, BrCpri, and BrCsec may be attributed to the emissions, meteorological conditions, and photochemical oxidation. The inferred potential source spatial distributions of BC and BrCpri showed different patterns at the foothill and summit. The results underlined the primary emission effects (including BC and BrCpri) at the foothill and the importance of BrCsec at the summit, respectively.

源语言英语
文章编号157814
期刊Science of the Total Environment
848
DOI
出版状态已出版 - 20 11月 2022

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