Chirality and polarity in the f-block borates M4[B 16O26(OH)4(H2O)3Cl 4] (M = Sm, Eu, Gd, Pu, Am, Cm, and Cf)

Matthew J. Polinski; Kristen A. Pace; Jared T. Stritzinger; Jian Lin; Justin N. Cross; Samantha K. Cary; Shelley M.Van Cleve; Evgeny V. Alekseev; Thomas E. Albrecht-Schmitt

doi:10.1002/chem.201403820

Chirality and polarity in the f-block borates M₄[B ₁₆O₂₆(OH)₄(H₂O)₃Cl ₄] (M = Sm, Eu, Gd, Pu, Am, Cm, and Cf)

Matthew J. Polinski
, Kristen A. Pace
, Jared T. Stritzinger
, Jian Lin
, Justin N. Cross
, Samantha K. Cary
, Shelley M.Van Cleve
, Evgeny V. Alekseev
, Thomas E. Albrecht-Schmitt

Florida State University
Oak Ridge National Laboratory
Jülich Research Centre
RWTH Aachen University

科研成果: 期刊稿件 › 文章 › 同行评审

24 引用（Scopus）

摘要

The reactions of trivalent lanthanides and actinides with molten boric acid in high chloride concentrations result in the formation of M₄[B ₁₆O₂₆(OH)₄(H₂O)₃Cl ₄] (M=Sm, Eu, Gd, Pu, Am, Cm, Cf). This cubic structure type is remarkably complex and displays both chirality and polarity. The polymeric borate network forms helical features that are linked via two different types of nine-coordinate f-element environments. The f-f transitions are unusually intense and result in dark coloration of these compounds with actinides.

源语言	英语
页（从-至）	9892-9896
页数	5
期刊	Chemistry - A European Journal
卷	20
期	32
DOI	https://doi.org/10.1002/chem.201403820
出版状态	已出版 - 4 8月 2014
已对外发布	是

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title = "Chirality and polarity in the f-block borates M4[B 16O26(OH)4(H2O)3Cl 4] (M = Sm, Eu, Gd, Pu, Am, Cm, and Cf)",

abstract = "The reactions of trivalent lanthanides and actinides with molten boric acid in high chloride concentrations result in the formation of M4[B 16O26(OH)4(H2O)3Cl 4] (M=Sm, Eu, Gd, Pu, Am, Cm, Cf). This cubic structure type is remarkably complex and displays both chirality and polarity. The polymeric borate network forms helical features that are linked via two different types of nine-coordinate f-element environments. The f-f transitions are unusually intense and result in dark coloration of these compounds with actinides.",

keywords = "actinides, americium, californium, curium, lanthanides, plutonium",

author = "Polinski, \{Matthew J.\} and Pace, \{Kristen A.\} and Stritzinger, \{Jared T.\} and Jian Lin and Cross, \{Justin N.\} and Cary, \{Samantha K.\} and Cleve, \{Shelley M.Van\} and Alekseev, \{Evgeny V.\} and Albrecht-Schmitt, \{Thomas E.\}",

year = "2014",

month = aug,

day = "4",

doi = "10.1002/chem.201403820",

language = "英语",

volume = "20",

pages = "9892--9896",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "John Wiley and Sons Inc",

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TY - JOUR

T1 - Chirality and polarity in the f-block borates M4[B 16O26(OH)4(H2O)3Cl 4] (M = Sm, Eu, Gd, Pu, Am, Cm, and Cf)

AU - Polinski, Matthew J.

AU - Pace, Kristen A.

AU - Stritzinger, Jared T.

AU - Lin, Jian

AU - Cross, Justin N.

AU - Cary, Samantha K.

AU - Cleve, Shelley M.Van

AU - Alekseev, Evgeny V.

AU - Albrecht-Schmitt, Thomas E.

PY - 2014/8/4

Y1 - 2014/8/4

N2 - The reactions of trivalent lanthanides and actinides with molten boric acid in high chloride concentrations result in the formation of M4[B 16O26(OH)4(H2O)3Cl 4] (M=Sm, Eu, Gd, Pu, Am, Cm, Cf). This cubic structure type is remarkably complex and displays both chirality and polarity. The polymeric borate network forms helical features that are linked via two different types of nine-coordinate f-element environments. The f-f transitions are unusually intense and result in dark coloration of these compounds with actinides.

AB - The reactions of trivalent lanthanides and actinides with molten boric acid in high chloride concentrations result in the formation of M4[B 16O26(OH)4(H2O)3Cl 4] (M=Sm, Eu, Gd, Pu, Am, Cm, Cf). This cubic structure type is remarkably complex and displays both chirality and polarity. The polymeric borate network forms helical features that are linked via two different types of nine-coordinate f-element environments. The f-f transitions are unusually intense and result in dark coloration of these compounds with actinides.

KW - actinides

KW - americium

KW - californium

KW - curium

KW - lanthanides

KW - plutonium

UR - https://www.scopus.com/pages/publications/84905226612

U2 - 10.1002/chem.201403820

DO - 10.1002/chem.201403820

M3 - 文章

AN - SCOPUS:84905226612

SN - 0947-6539

VL - 20

SP - 9892

EP - 9896

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 32

ER -

Chirality and polarity in the f-block borates M4[B 16O26(OH)4(H2O)3Cl 4] (M = Sm, Eu, Gd, Pu, Am, Cm, and Cf)

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Chirality and polarity in the f-block borates M₄[B ₁₆O₂₆(OH)₄(H₂O)₃Cl ₄] (M = Sm, Eu, Gd, Pu, Am, Cm, and Cf)