Angle-controlled synthesis and redox properties of a tetraphenylethene-based hexacationic triangular macrocycle

Yang Yu; Xiaowen Song; Yawen Li; Pingxia Wang; Lin Cheng; Ying Yang; Gang He; Liping Cao

doi:10.1039/d5cc03589a

Angle-controlled synthesis and redox properties of a tetraphenylethene-based hexacationic triangular macrocycle

Yang Yu
, Xiaowen Song
, Yawen Li
, Pingxia Wang
, Lin Cheng
, Ying Yang
, Gang He
, Liping Cao

前沿科学技术研究院

Northwest University China
Xi'an Jiaotong University

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

A tetraphenylethene-based hexacationic triangular macrocycle (T⁶⁺·6PF₆⁻) was synthesized via the Zincke reaction using an angle-controlled synthesis strategy. Under chemical or electrochemical reduction conditions, T⁶⁺·6PF₆⁻ can undergo two-step reversible and stable redox transformations, accompanied by a distinct visual color change.

源语言	英语
页（从-至）	13193-13196
页数	4
期刊	Chemical Communications
卷	61
期	70
DOI	https://doi.org/10.1039/d5cc03589a
出版状态	已出版 - 26 8月 2025

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10.1039/d5cc03589a

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abstract = "A tetraphenylethene-based hexacationic triangular macrocycle (T6+·6PF6−) was synthesized via the Zincke reaction using an angle-controlled synthesis strategy. Under chemical or electrochemical reduction conditions, T6+·6PF6− can undergo two-step reversible and stable redox transformations, accompanied by a distinct visual color change.",

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AU - Yu, Yang

AU - Song, Xiaowen

AU - Li, Yawen

AU - Wang, Pingxia

AU - Cheng, Lin

AU - Yang, Ying

AU - He, Gang

AU - Cao, Liping

PY - 2025/8/26

Y1 - 2025/8/26

N2 - A tetraphenylethene-based hexacationic triangular macrocycle (T6+·6PF6−) was synthesized via the Zincke reaction using an angle-controlled synthesis strategy. Under chemical or electrochemical reduction conditions, T6+·6PF6− can undergo two-step reversible and stable redox transformations, accompanied by a distinct visual color change.

AB - A tetraphenylethene-based hexacationic triangular macrocycle (T6+·6PF6−) was synthesized via the Zincke reaction using an angle-controlled synthesis strategy. Under chemical or electrochemical reduction conditions, T6+·6PF6− can undergo two-step reversible and stable redox transformations, accompanied by a distinct visual color change.

UR - https://www.scopus.com/pages/publications/105013993225

U2 - 10.1039/d5cc03589a

DO - 10.1039/d5cc03589a

M3 - 文章

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AN - SCOPUS:105013993225

SN - 1359-7345

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SP - 13193

EP - 13196

JO - Chemical Communications

JF - Chemical Communications

IS - 70

ER -

Angle-controlled synthesis and redox properties of a tetraphenylethene-based hexacationic triangular macrocycle

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