Access to azonanes via Pd-catalyzed decarboxylative [5 + 4] cycloaddition with exclusive regioselectivity

Yin Liu; Yicheng He; Yang Liu; Kun Wei; Wusheng Guo

doi:10.1039/d1qo01405f

Access to azonanes via Pd-catalyzed decarboxylative [5 + 4] cycloaddition with exclusive regioselectivity

Yin Liu
, Yicheng He
, Yang Liu
, Kun Wei
, Wusheng Guo

前沿科学技术研究院

South China University of Technology
Xi'an Jiaotong University

科研成果: 期刊稿件 › 文章 › 同行评审

33 引用（Scopus）

摘要

A highly efficient approach for the synthesis of azonanes via Pd-catalyzed decarboxylative [5 + 4] cycloaddition has been developed. This procedure utilizes methylene cyclic carbonates as a C5-dipole and 1-azadiene as a C4-synthon. The reactions could be performed at room temperature. The protocol features wide functional group tolerance with exclusive regioselectivity and generates CO2 as the only byproduct.

源语言	英语
页（从-至）	7004-7008
页数	5
期刊	Organic Chemistry Frontiers
卷	8
期	24
DOI	https://doi.org/10.1039/d1qo01405f
出版状态	已出版 - 21 12月 2021

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abstract = "A highly efficient approach for the synthesis of azonanes via Pd-catalyzed decarboxylative [5 + 4] cycloaddition has been developed. This procedure utilizes methylene cyclic carbonates as a C5-dipole and 1-azadiene as a C4-synthon. The reactions could be performed at room temperature. The protocol features wide functional group tolerance with exclusive regioselectivity and generates CO2 as the only byproduct.",

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AU - He, Yicheng

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AU - Wei, Kun

AU - Guo, Wusheng

PY - 2021/12/21

Y1 - 2021/12/21

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AB - A highly efficient approach for the synthesis of azonanes via Pd-catalyzed decarboxylative [5 + 4] cycloaddition has been developed. This procedure utilizes methylene cyclic carbonates as a C5-dipole and 1-azadiene as a C4-synthon. The reactions could be performed at room temperature. The protocol features wide functional group tolerance with exclusive regioselectivity and generates CO2 as the only byproduct.

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Access to azonanes via Pd-catalyzed decarboxylative [5 + 4] cycloaddition with exclusive regioselectivity

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