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A skeletal double gyroid formed by single coaxial bundles of catechol based bolapolyphiles

  • Silvio Poppe
  • , Changlong Chen
  • , Feng Liu
  • , Carsten Tschierske
  • Martin Luther University Halle-Wittenberg
  • Xi'an Jiaotong University

科研成果: 期刊稿件文章同行评审

23 引用 (Scopus)

摘要

A bolapolyphile, derived from a linear p-terphenyl core with glycerol groups at each end and two octadecyl chains fixed to the same side of the π-conjugated rod, is synthesized and is found to form a new type of self-assembled cubic LC phase with the Ia3d lattice. Each unit cell involves 16 polar aggregates interconnected by 24 coaxial rod-bundles at the single-molecule length, forming two interwoven skeletal networks with three-way junctions, being separated by a continuum of the lateral alkyl chains located around the gyroid minimal surface.

源语言英语
页(从-至)11196-11199
页数4
期刊Chemical Communications
54
79
DOI
出版状态已出版 - 2018

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