A metal-free transformation of alkynes to carbonyls directed by remote OH group

Dao Qian Chen; Chun Huan Guo; Heng Rui Zhang; Dong Po Jin; Xue Song Li; Pin Gao; Xin Xing Wu; Xue Yuan Liu; Yong Min Liang

doi:10.1039/c6gc01141a

A metal-free transformation of alkynes to carbonyls directed by remote OH group

Dao Qian Chen
, Chun Huan Guo
, Heng Rui Zhang
, Dong Po Jin
, Xue Song Li
, Pin Gao
, Xin Xing Wu
, Xue Yuan Liu
, Yong Min Liang

化学学院

Lanzhou University

科研成果: 期刊稿件 › 文章 › 同行评审

14 引用（Scopus）

摘要

A remote OH group-directed metal-free transformation of alkynes to carbonyl compounds has been developed. Using only HOAc and EtOH solvent, this reaction elegantly converts alkynes into valuable ketones by remote hydroxyl group activation. Through comparison and isotope labeling experiments, it was confirmed that the process operates via a hydration reaction involving an acetic acid molecule, instead of a water molecule.

源语言	英语
页（从-至）	4176-4180
页数	5
期刊	Green Chemistry
卷	18
期	15
DOI	https://doi.org/10.1039/c6gc01141a
出版状态	已出版 - 2016

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10.1039/c6gc01141a

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abstract = "A remote OH group-directed metal-free transformation of alkynes to carbonyl compounds has been developed. Using only HOAc and EtOH solvent, this reaction elegantly converts alkynes into valuable ketones by remote hydroxyl group activation. Through comparison and isotope labeling experiments, it was confirmed that the process operates via a hydration reaction involving an acetic acid molecule, instead of a water molecule.",

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AU - Chen, Dao Qian

AU - Guo, Chun Huan

AU - Zhang, Heng Rui

AU - Jin, Dong Po

AU - Li, Xue Song

AU - Gao, Pin

AU - Wu, Xin Xing

AU - Liu, Xue Yuan

AU - Liang, Yong Min

PY - 2016

Y1 - 2016

N2 - A remote OH group-directed metal-free transformation of alkynes to carbonyl compounds has been developed. Using only HOAc and EtOH solvent, this reaction elegantly converts alkynes into valuable ketones by remote hydroxyl group activation. Through comparison and isotope labeling experiments, it was confirmed that the process operates via a hydration reaction involving an acetic acid molecule, instead of a water molecule.

AB - A remote OH group-directed metal-free transformation of alkynes to carbonyl compounds has been developed. Using only HOAc and EtOH solvent, this reaction elegantly converts alkynes into valuable ketones by remote hydroxyl group activation. Through comparison and isotope labeling experiments, it was confirmed that the process operates via a hydration reaction involving an acetic acid molecule, instead of a water molecule.

UR - https://www.scopus.com/pages/publications/84979497399

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DO - 10.1039/c6gc01141a

M3 - 文章

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SN - 1463-9262

VL - 18

SP - 4176

EP - 4180

JO - Green Chemistry

JF - Green Chemistry

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ER -

A metal-free transformation of alkynes to carbonyls directed by remote OH group

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