A Long Cycle-Life High-Voltage Spinel Lithium-Ion Battery Electrode Achieved by Site-Selective Doping

Gemeng Liang; Zhibin Wu; Christophe Didier; Wenchao Zhang; Jing Cuan; Baohua Li; Kuan Yu Ko; Po Yang Hung; Cheng Zhang Lu; Yuanzhen Chen; Grzegorz Leniec; Sławomir Maksymilian Kaczmarek; Bernt Johannessen; Lars Thomsen; Vanessa K. Peterson; Wei Kong Pang; Zaiping Guo

doi:10.1002/anie.202001454

A Long Cycle-Life High-Voltage Spinel Lithium-Ion Battery Electrode Achieved by Site-Selective Doping

Gemeng Liang
, Zhibin Wu
, Christophe Didier
, Wenchao Zhang
, Jing Cuan
, Baohua Li
, Kuan Yu Ko
, Po Yang Hung
, Cheng Zhang Lu
, Yuanzhen Chen
, Grzegorz Leniec
, Sławomir Maksymilian Kaczmarek
, Bernt Johannessen
, Lars Thomsen
, Vanessa K. Peterson
, Wei Kong Pang
, Zaiping Guo

材料科学与工程学院

University of Wollongong
Australian Nuclear Science and Technology Organisation
Tsinghua University
Industrial Technology Research Institute of Taiwan
West Pomeranian University of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

207 引用（Scopus）

摘要

Spinel LiNi_0.5Mn_1.5O₄ (LNMO) is a promising cathode candidate for the next-generation high energy-density lithium-ion batteries (LIBs). Unfortunately, the application of LNMO is hindered by its poor cycle stability. Now, site-selectively doped LNMO electrode is prepared with exceptional durability. In this work, Mg is selectively doped onto both tetrahedral (8a) and octahedral (16c) sites in the Fd (Formula presented.) m structure. This site-selective doping not only suppresses unfavorable two-phase reactions and stabilizes the LNMO structure against structural deformation, but also mitigates the dissolution of Mn during cycling. Mg-doped LNMOs exhibit extraordinarily stable electrochemical performance in both half-cells and prototype full-batteries with novel TiNb₂O₇ counter-electrodes. This work pioneers an atomic-doping engineering strategy for electrode materials that could be extended to other energy materials to create high-performance devices.

源语言	英语
页（从-至）	10594-10602
页数	9
期刊	Angewandte Chemie - International Edition
卷	59
期	26
DOI	https://doi.org/10.1002/anie.202001454
出版状态	已出版 - 22 6月 2020

联合国可持续发展目标

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可持续发展目标 7 经济适用的清洁能源

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10.1002/anie.202001454

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Liang, G., Wu, Z., Didier, C., Zhang, W., Cuan, J., Li, B., Ko, K. Y., Hung, P. Y., Lu, C. Z., Chen, Y., Leniec, G., Kaczmarek, S. M., Johannessen, B., Thomsen, L., Peterson, V. K., Pang, W. K., & Guo, Z. (2020). A Long Cycle-Life High-Voltage Spinel Lithium-Ion Battery Electrode Achieved by Site-Selective Doping. Angewandte Chemie - International Edition, 59(26), 10594-10602. https://doi.org/10.1002/anie.202001454

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title = "A Long Cycle-Life High-Voltage Spinel Lithium-Ion Battery Electrode Achieved by Site-Selective Doping",

abstract = "Spinel LiNi0.5Mn1.5O4 (LNMO) is a promising cathode candidate for the next-generation high energy-density lithium-ion batteries (LIBs). Unfortunately, the application of LNMO is hindered by its poor cycle stability. Now, site-selectively doped LNMO electrode is prepared with exceptional durability. In this work, Mg is selectively doped onto both tetrahedral (8a) and octahedral (16c) sites in the Fd (Formula presented.) m structure. This site-selective doping not only suppresses unfavorable two-phase reactions and stabilizes the LNMO structure against structural deformation, but also mitigates the dissolution of Mn during cycling. Mg-doped LNMOs exhibit extraordinarily stable electrochemical performance in both half-cells and prototype full-batteries with novel TiNb2O7 counter-electrodes. This work pioneers an atomic-doping engineering strategy for electrode materials that could be extended to other energy materials to create high-performance devices.",

keywords = "high energy density, lithium-ion batteries, long cycle life, site-selective doping, spinel cathodes",

author = "Gemeng Liang and Zhibin Wu and Christophe Didier and Wenchao Zhang and Jing Cuan and Baohua Li and Ko, \{Kuan Yu\} and Hung, \{Po Yang\} and Lu, \{Cheng Zhang\} and Yuanzhen Chen and Grzegorz Leniec and Kaczmarek, \{S{\l}awomir Maksymilian\} and Bernt Johannessen and Lars Thomsen and Peterson, \{Vanessa K.\} and Pang, \{Wei Kong\} and Zaiping Guo",

note = "Publisher Copyright: {\textcopyright} 2020 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2020",

month = jun,

day = "22",

doi = "10.1002/anie.202001454",

language = "英语",

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Liang, G, Wu, Z, Didier, C, Zhang, W, Cuan, J, Li, B, Ko, KY, Hung, PY, Lu, CZ, Chen, Y, Leniec, G, Kaczmarek, SM, Johannessen, B, Thomsen, L, Peterson, VK, Pang, WK & Guo, Z 2020, 'A Long Cycle-Life High-Voltage Spinel Lithium-Ion Battery Electrode Achieved by Site-Selective Doping', Angewandte Chemie - International Edition, 卷 59, 号码 26, 页码 10594-10602. https://doi.org/10.1002/anie.202001454

TY - JOUR

T1 - A Long Cycle-Life High-Voltage Spinel Lithium-Ion Battery Electrode Achieved by Site-Selective Doping

AU - Liang, Gemeng

AU - Wu, Zhibin

AU - Didier, Christophe

AU - Zhang, Wenchao

AU - Cuan, Jing

AU - Li, Baohua

AU - Ko, Kuan Yu

AU - Hung, Po Yang

AU - Lu, Cheng Zhang

AU - Chen, Yuanzhen

AU - Leniec, Grzegorz

AU - Kaczmarek, Sławomir Maksymilian

AU - Johannessen, Bernt

AU - Thomsen, Lars

AU - Peterson, Vanessa K.

AU - Pang, Wei Kong

AU - Guo, Zaiping

PY - 2020/6/22

Y1 - 2020/6/22

N2 - Spinel LiNi0.5Mn1.5O4 (LNMO) is a promising cathode candidate for the next-generation high energy-density lithium-ion batteries (LIBs). Unfortunately, the application of LNMO is hindered by its poor cycle stability. Now, site-selectively doped LNMO electrode is prepared with exceptional durability. In this work, Mg is selectively doped onto both tetrahedral (8a) and octahedral (16c) sites in the Fd (Formula presented.) m structure. This site-selective doping not only suppresses unfavorable two-phase reactions and stabilizes the LNMO structure against structural deformation, but also mitigates the dissolution of Mn during cycling. Mg-doped LNMOs exhibit extraordinarily stable electrochemical performance in both half-cells and prototype full-batteries with novel TiNb2O7 counter-electrodes. This work pioneers an atomic-doping engineering strategy for electrode materials that could be extended to other energy materials to create high-performance devices.

AB - Spinel LiNi0.5Mn1.5O4 (LNMO) is a promising cathode candidate for the next-generation high energy-density lithium-ion batteries (LIBs). Unfortunately, the application of LNMO is hindered by its poor cycle stability. Now, site-selectively doped LNMO electrode is prepared with exceptional durability. In this work, Mg is selectively doped onto both tetrahedral (8a) and octahedral (16c) sites in the Fd (Formula presented.) m structure. This site-selective doping not only suppresses unfavorable two-phase reactions and stabilizes the LNMO structure against structural deformation, but also mitigates the dissolution of Mn during cycling. Mg-doped LNMOs exhibit extraordinarily stable electrochemical performance in both half-cells and prototype full-batteries with novel TiNb2O7 counter-electrodes. This work pioneers an atomic-doping engineering strategy for electrode materials that could be extended to other energy materials to create high-performance devices.

KW - high energy density

KW - lithium-ion batteries

KW - long cycle life

KW - site-selective doping

KW - spinel cathodes

UR - https://www.scopus.com/pages/publications/85083431331

U2 - 10.1002/anie.202001454

DO - 10.1002/anie.202001454

M3 - 文章

C2 - 32207203

AN - SCOPUS:85083431331

SN - 1433-7851

VL - 59

SP - 10594

EP - 10602

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 26

ER -

A Long Cycle-Life High-Voltage Spinel Lithium-Ion Battery Electrode Achieved by Site-Selective Doping

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