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A fully electrically driven hydrogen direct reduction process for zero-carbon green steel production

  • Zeng Liang
  • , Jianliang Zhang
  • , Kejiang Li
  • , Lei Shao
  • , Zhengjian Liu
  • , Zonghao Yang
  • , Chunhe Jiang
  • , Shan Ren
  • , Alberto N. Conejo
  • University of Science and Technology Beijing
  • Northeastern University China

科研成果: 期刊稿件文章同行评审

9 引用 (Scopus)

摘要

As one of the most promising pathways for producing zero-carbon green steel, hydrogen-based shaft furnaces face significant challenges related to the heating, transportation, and injection of high-temperature (950-1050 °C) H2. A production process that integrates induction heating with low-temperature hydrogen injection into the shaft furnace has been proposed. The feasibility of producing high-quality direct reduced iron (DRI) through hydrogen reduction via induction heating has been validated at the laboratory scale. Utilizing advanced in situ XRD analysis, the reduction pathway of iron oxides (Fe2O3 → Fe3O4 → FeO → Fe) was clearly delineated, revealing the phase transition processes at each stage. Induction heating performance varies significantly with the reduction degree: Fe2O3 initially lacks heating capability, but reduction to Fe3O4 enhances magnetic properties, improving efficiency. Further reduction to FeO decreases efficiency, which rises again when metallic Fe becomes the dominant phase. Under induction heating, DRI samples reach over 900 °C within seconds, demonstrating strong heating potential. Integrating electrolytic hydrogen generation with induction heating produces high-quality DRI, achieving a 96.04% reduction in 40 minutes at 750 °C. These findings establish a fully green, electric-driven direct reduction system, eliminating the need for high-temperature reducing gases and advancing sustainable iron production.

源语言英语
页(从-至)4766-4778
页数13
期刊Green Chemistry
27
17
DOI
出版状态已出版 - 25 3月 2025

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