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Volumetric properties of binary mixtures of {difluoromethane (R32) + trans-1,3,3,3-tetrafluoropropene (R1234ze(E))} at temperatures from 283.15 K to 363.15 K and pressures up to 100 MPa

  • Tao Jia
  • , Shengshan Bi
  • , Xiaozhen Hu
  • , Xianyang Meng
  • , Jiangtao Wu

Research output: Contribution to journalArticlepeer-review

32 Scopus citations

Abstract

Values of experimental density of difluoromethane (R32) and five compositions of {R32 + trans-1,3,3,3-tetrafluoropropene (R1234ze(E))} binary mixtures are reported over the temperature range from 283 K to 363 K and at pressures up to 100 MPa with a vibrating-tube densimeter. The excess molar volumes were calculated from experimental results and fitted to the Redlich-Kister equation. The maximum standard deviation and average standard deviations of the experimental and calculated values of excess molar volume from Redlich-Kister equation are 0.07789 cm3·mol-1 and 0.01645 cm3·mol-1, respectively.

Original languageEnglish
Pages (from-to)54-63
Number of pages10
JournalJournal of Chemical Thermodynamics
Volume101
DOIs
StatePublished - 1 Oct 2016

Keywords

  • Density
  • Excess molar volume
  • R1234ze(E)
  • R32
  • Vibrating-tube densimeter

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