TY - GEN
T1 - Vapor-liquid equilibrium of H2/CO2and H2/N2/CO2mixture, the liquefaction technology related to the supercritical water gasification products
AU - Wu, Hongtu
AU - Jin, Hui
N1 - Publisher Copyright:
© 2023 University of Split, FESB.
PY - 2023
Y1 - 2023
N2 - In this paper, the dew point and liquid phase composition of H2/CO2 and H2/CO2/N2 mixtures at phase equilibrium calculated by PR-BM equation and Van Der Waal mixing rule with commercial MATLAB software are introduced, it is of theoretical significance for the wide application of the products of supercritical water gasification. First, the results obtained by the self-programming code are verified with the experimental data, the experimental data and simulation results of two kinds of CO2/H2 mixtures and two kinds of CO2/N2/H2 mixtures were compared. The average percentage deviation was 2.69%, 4.05%, 2.22%, 1.20%, respectively. Thus the absolute deviations of the mixtures are within the acceptable range, therefore, the model proposed in this paper can well predict the dew point of the mixtures composed of H2/CO2 or H2/CO2/N2.Afterwards, the dew point and the CO2 content in the liquid phase of common H2/CO2 and H2/CO2/N2 vapor mixtures in supercritical water gasification products were predicted, and a series of analysis and discussion were conducted on the predicted results finally.
AB - In this paper, the dew point and liquid phase composition of H2/CO2 and H2/CO2/N2 mixtures at phase equilibrium calculated by PR-BM equation and Van Der Waal mixing rule with commercial MATLAB software are introduced, it is of theoretical significance for the wide application of the products of supercritical water gasification. First, the results obtained by the self-programming code are verified with the experimental data, the experimental data and simulation results of two kinds of CO2/H2 mixtures and two kinds of CO2/N2/H2 mixtures were compared. The average percentage deviation was 2.69%, 4.05%, 2.22%, 1.20%, respectively. Thus the absolute deviations of the mixtures are within the acceptable range, therefore, the model proposed in this paper can well predict the dew point of the mixtures composed of H2/CO2 or H2/CO2/N2.Afterwards, the dew point and the CO2 content in the liquid phase of common H2/CO2 and H2/CO2/N2 vapor mixtures in supercritical water gasification products were predicted, and a series of analysis and discussion were conducted on the predicted results finally.
KW - liquefaction
KW - supercritical water gasification
KW - vapor-liquid equilibrium
UR - https://www.scopus.com/pages/publications/85168118063
U2 - 10.23919/SpliTech58164.2023.10193254
DO - 10.23919/SpliTech58164.2023.10193254
M3 - 会议稿件
AN - SCOPUS:85168118063
T3 - 2023 8th International Conference on Smart and Sustainable Technologies, SpliTech 2023
BT - 2023 8th International Conference on Smart and Sustainable Technologies, SpliTech 2023
A2 - Solic, Petar
A2 - Nizetic, Sandro
A2 - Rodrigues, Joel J. P. C.
A2 - Rodrigues, Joel J. P. C.
A2 - Rodrigues, Joel J. P. C.
A2 - Lopez-de-Ipina Gonzalez-de-Artaza, Diego
A2 - Perkovic, Toni
A2 - Catarinucci, Luca
A2 - Patrono, Luigi
PB - Institute of Electrical and Electronics Engineers Inc.
T2 - 8th International Conference on Smart and Sustainable Technologies, SpliTech 2023
Y2 - 20 June 2023 through 23 June 2023
ER -