Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M 2Te 4O 11]X 2 (M = Pu, Ce, Zr; X = Cl, Br)

Jian Lin; Justin N. Cross; Juan Diwu; Matthew J. Polinski; Eric M. Villa; Thomas E. Albrecht-Schmitt

doi:10.1021/ic301846g

Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M ₂Te ₄O ₁₁]X ₂ (M = Pu, Ce, Zr; X = Cl, Br)

Jian Lin
, Justin N. Cross
, Juan Diwu
, Matthew J. Polinski
, Eric M. Villa
, Thomas E. Albrecht-Schmitt

University of Notre Dame
Florida State University

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

Four isotypic cationic layered materials, [Pu ₂Te ₄O ₁₁]Cl ₂, [Ce ₂Te ₄O ₁₁]Cl ₂, [Zr ₂Te ₄O ₁₁] Cl ₂, and [Zr ₂Te ₄O ₁₁]Br ₂, have been prepared under hydrothermal conditions. Single crystal diffraction studies reveal that these materials possess cationic Pu/Ce/Zr tellurite layers with halides as interlamellar charge-balancing anions. The Pu ^IV, Ce ^IV, and Zr ^IV centers of the cationic layers exhibit a quite rare pentagonal bipyramid coordination environment.

Original language	English
Pages (from-to)	11949-11954
Number of pages	6
Journal	Inorganic Chemistry
Volume	51
Issue number	21
DOIs	https://doi.org/10.1021/ic301846g
State	Published - 5 Nov 2012
Externally published	Yes

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title = "Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M 2Te 4O 11]X 2 (M = Pu, Ce, Zr; X = Cl, Br)",

abstract = "Four isotypic cationic layered materials, [Pu 2Te 4O 11]Cl 2, [Ce 2Te 4O 11]Cl 2, [Zr 2Te 4O 11] Cl 2, and [Zr 2Te 4O 11]Br 2, have been prepared under hydrothermal conditions. Single crystal diffraction studies reveal that these materials possess cationic Pu/Ce/Zr tellurite layers with halides as interlamellar charge-balancing anions. The Pu IV, Ce IV, and Zr IV centers of the cationic layers exhibit a quite rare pentagonal bipyramid coordination environment.",

author = "Jian Lin and Cross, \{Justin N.\} and Juan Diwu and Polinski, \{Matthew J.\} and Villa, \{Eric M.\} and Albrecht-Schmitt, \{Thomas E.\}",

year = "2012",

month = nov,

day = "5",

doi = "10.1021/ic301846g",

language = "英语",

volume = "51",

pages = "11949--11954",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M 2Te 4O 11]X 2 (M = Pu, Ce, Zr; X = Cl, Br)

AU - Lin, Jian

AU - Cross, Justin N.

AU - Diwu, Juan

AU - Polinski, Matthew J.

AU - Villa, Eric M.

AU - Albrecht-Schmitt, Thomas E.

PY - 2012/11/5

Y1 - 2012/11/5

N2 - Four isotypic cationic layered materials, [Pu 2Te 4O 11]Cl 2, [Ce 2Te 4O 11]Cl 2, [Zr 2Te 4O 11] Cl 2, and [Zr 2Te 4O 11]Br 2, have been prepared under hydrothermal conditions. Single crystal diffraction studies reveal that these materials possess cationic Pu/Ce/Zr tellurite layers with halides as interlamellar charge-balancing anions. The Pu IV, Ce IV, and Zr IV centers of the cationic layers exhibit a quite rare pentagonal bipyramid coordination environment.

AB - Four isotypic cationic layered materials, [Pu 2Te 4O 11]Cl 2, [Ce 2Te 4O 11]Cl 2, [Zr 2Te 4O 11] Cl 2, and [Zr 2Te 4O 11]Br 2, have been prepared under hydrothermal conditions. Single crystal diffraction studies reveal that these materials possess cationic Pu/Ce/Zr tellurite layers with halides as interlamellar charge-balancing anions. The Pu IV, Ce IV, and Zr IV centers of the cationic layers exhibit a quite rare pentagonal bipyramid coordination environment.

UR - https://www.scopus.com/pages/publications/84868368045

U2 - 10.1021/ic301846g

DO - 10.1021/ic301846g

M3 - 文章

AN - SCOPUS:84868368045

SN - 0020-1669

VL - 51

SP - 11949

EP - 11954

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 21

ER -

Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M ₂Te ₄O ₁₁]X ₂ (M = Pu, Ce, Zr; X = Cl, Br)

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