Unprecedented (3,9)-connected (42.6)3(4 66.21.89) net constructed by trinuclear mixed-valence cobalt clusters

Xian Ming Zhang; Yan Zhen Zheng; Cui Rui Li; Wei Xiong Zhang; Xiao Ming Chen

doi:10.1021/cg070038o

Unprecedented (3,9)-connected (4².6)₃(4 ⁶6.²¹.8⁹) net constructed by trinuclear mixed-valence cobalt clusters

Xian Ming Zhang
, Yan Zhen Zheng
, Cui Rui Li
, Wei Xiong Zhang
, Xiao Ming Chen

Shanxi Normal University
Sun Yat-Sen University

Research output: Contribution to journal › Article › peer-review

136 Scopus citations

Abstract

A solvothermal reaction of Co₂O₃, CoSO₄, pyridine-3,5-dicarboxylic acid, and H₂O₂ in an aqueous MeCN solution yielded a three-dimensional coordination framework [Co ₃(OH)(pdc)₃]·H₂O (1) (pdc = pyridine-3,5-dicarboxylate). Compound 1 shows an unprecedented (3,9)-connected (4².6)₃(4⁶.6²¹.8⁹) topology in which hydroxycentered mixed-valence Co₃(OH)(CO ₂)₆ clusters act as nine-connected nodes of a tricapped trigonal prism, and pdc groups act as three-connected nodes of trigonal geometry.

Original language	English
Pages (from-to)	980-983
Number of pages	4
Journal	Crystal Growth and Design
Volume	7
Issue number	5
DOIs	https://doi.org/10.1021/cg070038o
State	Published - May 2007
Externally published	Yes

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title = "Unprecedented (3,9)-connected (42.6)3(4 66.21.89) net constructed by trinuclear mixed-valence cobalt clusters",

abstract = "A solvothermal reaction of Co2O3, CoSO4, pyridine-3,5-dicarboxylic acid, and H2O2 in an aqueous MeCN solution yielded a three-dimensional coordination framework [Co 3(OH)(pdc)3]·H2O (1) (pdc = pyridine-3,5-dicarboxylate). Compound 1 shows an unprecedented (3,9)-connected (42.6)3(46.621.89) topology in which hydroxycentered mixed-valence Co3(OH)(CO 2)6 clusters act as nine-connected nodes of a tricapped trigonal prism, and pdc groups act as three-connected nodes of trigonal geometry.",

author = "Zhang, \{Xian Ming\} and Zheng, \{Yan Zhen\} and Li, \{Cui Rui\} and Zhang, \{Wei Xiong\} and Chen, \{Xiao Ming\}",

year = "2007",

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doi = "10.1021/cg070038o",

language = "英语",

volume = "7",

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journal = "Crystal Growth and Design",

issn = "1528-7483",

publisher = "American Chemical Society",

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T1 - Unprecedented (3,9)-connected (42.6)3(4 66.21.89) net constructed by trinuclear mixed-valence cobalt clusters

AU - Zhang, Xian Ming

AU - Zheng, Yan Zhen

AU - Li, Cui Rui

AU - Zhang, Wei Xiong

AU - Chen, Xiao Ming

PY - 2007/5

Y1 - 2007/5

N2 - A solvothermal reaction of Co2O3, CoSO4, pyridine-3,5-dicarboxylic acid, and H2O2 in an aqueous MeCN solution yielded a three-dimensional coordination framework [Co 3(OH)(pdc)3]·H2O (1) (pdc = pyridine-3,5-dicarboxylate). Compound 1 shows an unprecedented (3,9)-connected (42.6)3(46.621.89) topology in which hydroxycentered mixed-valence Co3(OH)(CO 2)6 clusters act as nine-connected nodes of a tricapped trigonal prism, and pdc groups act as three-connected nodes of trigonal geometry.

AB - A solvothermal reaction of Co2O3, CoSO4, pyridine-3,5-dicarboxylic acid, and H2O2 in an aqueous MeCN solution yielded a three-dimensional coordination framework [Co 3(OH)(pdc)3]·H2O (1) (pdc = pyridine-3,5-dicarboxylate). Compound 1 shows an unprecedented (3,9)-connected (42.6)3(46.621.89) topology in which hydroxycentered mixed-valence Co3(OH)(CO 2)6 clusters act as nine-connected nodes of a tricapped trigonal prism, and pdc groups act as three-connected nodes of trigonal geometry.

UR - https://www.scopus.com/pages/publications/34249052162

U2 - 10.1021/cg070038o

DO - 10.1021/cg070038o

M3 - 文章

AN - SCOPUS:34249052162

SN - 1528-7483

VL - 7

SP - 980

EP - 983

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 5

ER -

Unprecedented (3,9)-connected (4².6)₃(4 ⁶6.²¹.8⁹) net constructed by trinuclear mixed-valence cobalt clusters

Abstract

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