Understanding a pentagonal-bipyramidal holmium(iii) complex with a record energy barrier for magnetisation reversal

Yan Ma; Yuan Qi Zhai; You Song Ding; Tian Han; Yan Zhen Zheng

doi:10.1039/d0cc00500b

Understanding a pentagonal-bipyramidal holmium(iii) complex with a record energy barrier for magnetisation reversal

Yan Ma
, Yuan Qi Zhai
, You Song Ding
, Tian Han
, Yan Zhen Zheng

Xi'an Jiaotong University

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

We report herein three pentagonal-bipyramidal holmium(iii) complexes sharing the formula [Ho(L)₂(py)₅][BPh₄], where L is the alkoxide ligand. For L = (OSi(CH₃)₃)^-, a record energy barrier for magnetization reversal (U_eff = 715(6) K) was revealed, which is due to the pure state transition of m_J = |±8〉 → m_J = |±7〉 → m_J = |±6〉.

Original language	English
Pages (from-to)	3979-3982
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	28
DOIs	https://doi.org/10.1039/d0cc00500b
State	Published - 11 Apr 2020

Access to Document

10.1039/d0cc00500b

Cite this

@article{3b746fa89a0f487d89c13c4c4964e468,

title = "Understanding a pentagonal-bipyramidal holmium(iii) complex with a record energy barrier for magnetisation reversal",

abstract = "We report herein three pentagonal-bipyramidal holmium(iii) complexes sharing the formula [Ho(L)2(py)5][BPh4], where L is the alkoxide ligand. For L = (OSi(CH3)3)-, a record energy barrier for magnetization reversal (Ueff = 715(6) K) was revealed, which is due to the pure state transition of mJ = |±8〉 → mJ = |±7〉 → mJ = |±6〉.",

author = "Yan Ma and Zhai, \{Yuan Qi\} and Ding, \{You Song\} and Tian Han and Zheng, \{Yan Zhen\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2020",

month = apr,

day = "11",

doi = "10.1039/d0cc00500b",

language = "英语",

volume = "56",

pages = "3979--3982",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "28",

}

TY - JOUR

T1 - Understanding a pentagonal-bipyramidal holmium(iii) complex with a record energy barrier for magnetisation reversal

AU - Ma, Yan

AU - Zhai, Yuan Qi

AU - Ding, You Song

AU - Han, Tian

AU - Zheng, Yan Zhen

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2020/4/11

Y1 - 2020/4/11

N2 - We report herein three pentagonal-bipyramidal holmium(iii) complexes sharing the formula [Ho(L)2(py)5][BPh4], where L is the alkoxide ligand. For L = (OSi(CH3)3)-, a record energy barrier for magnetization reversal (Ueff = 715(6) K) was revealed, which is due to the pure state transition of mJ = |±8〉 → mJ = |±7〉 → mJ = |±6〉.

AB - We report herein three pentagonal-bipyramidal holmium(iii) complexes sharing the formula [Ho(L)2(py)5][BPh4], where L is the alkoxide ligand. For L = (OSi(CH3)3)-, a record energy barrier for magnetization reversal (Ueff = 715(6) K) was revealed, which is due to the pure state transition of mJ = |±8〉 → mJ = |±7〉 → mJ = |±6〉.

UR - https://www.scopus.com/pages/publications/85083003408

U2 - 10.1039/d0cc00500b

DO - 10.1039/d0cc00500b

M3 - 文章

C2 - 32154531

AN - SCOPUS:85083003408

SN - 1359-7345

VL - 56

SP - 3979

EP - 3982

JO - Chemical Communications

JF - Chemical Communications

IS - 28

ER -

Understanding a pentagonal-bipyramidal holmium(iii) complex with a record energy barrier for magnetisation reversal

Abstract

Access to Document

Other files and links

Fingerprint

Cite this