Abstract
Two new porous lanthanide-organic frameworks, {[Ln2(HIDC) 3(H2O)2]·7H2O}n [Ln = Tb(1) and Eu(2), H3IDC = imidazole-4,5-dicarboxylic acid], were obtained under hydrothermal conditions. Both of them possess 3D frameworks containing 1D rectangle channels along a-axis. Topological analyses of two complexes reveal that they exhibit unusual 4-nodal (3,4)-connected network. Furthermore, their solid-state luminescent behaviors have been investigated at room temperature.
| Original language | English |
|---|---|
| Pages (from-to) | 826-830 |
| Number of pages | 5 |
| Journal | Inorganic Chemistry Communications |
| Volume | 14 |
| Issue number | 6 |
| DOIs | |
| State | Published - Jun 2011 |
| Externally published | Yes |
Keywords
- (3,4)-connected network topology
- Imidazole-4,5-dicarboxylic acid
- Luminescence
- Porous lanthanide-organic framework
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