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Two novel porous luminescent lanthanide-organic frameworks with new four-nodal (3,4)-connected network topology

  • Sheng Run Zheng
  • , Song Liang Cai
  • , Qing Yuan Yang
  • , Tian Tian Xiao
  • , Jun Fan
  • , Wei Guang Zhang
  • South China Normal University
  • Sun Yat-Sen University

Research output: Contribution to journalArticlepeer-review

28 Scopus citations

Abstract

Two new porous lanthanide-organic frameworks, {[Ln2(HIDC) 3(H2O)2]·7H2O}n [Ln = Tb(1) and Eu(2), H3IDC = imidazole-4,5-dicarboxylic acid], were obtained under hydrothermal conditions. Both of them possess 3D frameworks containing 1D rectangle channels along a-axis. Topological analyses of two complexes reveal that they exhibit unusual 4-nodal (3,4)-connected network. Furthermore, their solid-state luminescent behaviors have been investigated at room temperature.

Original languageEnglish
Pages (from-to)826-830
Number of pages5
JournalInorganic Chemistry Communications
Volume14
Issue number6
DOIs
StatePublished - Jun 2011
Externally publishedYes

Keywords

  • (3,4)-connected network topology
  • Imidazole-4,5-dicarboxylic acid
  • Luminescence
  • Porous lanthanide-organic framework

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