Transition-metal-free alkoxycarbonylation of aryl halides

Hua Zhang; Renyi Shi; Anxing Ding; Lijun Lu; Borui Chen; Aiwen Lei

doi:10.1002/anie.201206518

Transition-metal-free alkoxycarbonylation of aryl halides

Hua Zhang
, Renyi Shi
, Anxing Ding
, Lijun Lu
, Borui Chen
, Aiwen Lei

Research output: Contribution to journal › Article › peer-review

134 Scopus citations

Abstract

Transitions: The title reaction has been developed for the synthesis of a variety of tert-butyl benzoates by employing 1,10-phenanthroline as an additive. Various functional groups were tolerated and heteroaryl iodides were also suitable substrates. Preliminary mechanism studies were conducted and indicate the participation of radical intermediates.

Original language	English
Pages (from-to)	12542-12545
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	50
DOIs	https://doi.org/10.1002/anie.201206518
State	Published - 7 Dec 2012
Externally published	Yes

Keywords

arenes
carbonylation
electron transfer
radicals
synthetic methods

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10.1002/anie.201206518

Cite this

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title = "Transition-metal-free alkoxycarbonylation of aryl halides",

abstract = "Transitions: The title reaction has been developed for the synthesis of a variety of tert-butyl benzoates by employing 1,10-phenanthroline as an additive. Various functional groups were tolerated and heteroaryl iodides were also suitable substrates. Preliminary mechanism studies were conducted and indicate the participation of radical intermediates.",

keywords = "arenes, carbonylation, electron transfer, radicals, synthetic methods",

author = "Hua Zhang and Renyi Shi and Anxing Ding and Lijun Lu and Borui Chen and Aiwen Lei",

year = "2012",

month = dec,

day = "7",

doi = "10.1002/anie.201206518",

language = "英语",

volume = "51",

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journal = "Angewandte Chemie - International Edition",

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publisher = "John Wiley and Sons Ltd",

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T1 - Transition-metal-free alkoxycarbonylation of aryl halides

AU - Zhang, Hua

AU - Shi, Renyi

AU - Ding, Anxing

AU - Lu, Lijun

AU - Chen, Borui

AU - Lei, Aiwen

PY - 2012/12/7

Y1 - 2012/12/7

N2 - Transitions: The title reaction has been developed for the synthesis of a variety of tert-butyl benzoates by employing 1,10-phenanthroline as an additive. Various functional groups were tolerated and heteroaryl iodides were also suitable substrates. Preliminary mechanism studies were conducted and indicate the participation of radical intermediates.

AB - Transitions: The title reaction has been developed for the synthesis of a variety of tert-butyl benzoates by employing 1,10-phenanthroline as an additive. Various functional groups were tolerated and heteroaryl iodides were also suitable substrates. Preliminary mechanism studies were conducted and indicate the participation of radical intermediates.

KW - arenes

KW - carbonylation

KW - electron transfer

KW - radicals

KW - synthetic methods

UR - https://www.scopus.com/pages/publications/84870597758

U2 - 10.1002/anie.201206518

DO - 10.1002/anie.201206518

M3 - 文章

AN - SCOPUS:84870597758

SN - 1433-7851

VL - 51

SP - 12542

EP - 12545

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 50

ER -

Transition-metal-free alkoxycarbonylation of aryl halides

Abstract

Keywords

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