Ti-doped MgO thin film by magnetron sputtering for cesium frequency standard

The main component of magnetically selected cesium frequency standard is electron multiplier. Its working principle is to magnify cesium beam signal by emitting secondary electron through surface of material. Magnesium oxide (MgO) has been adopted due to its excellent capability to emit secondary electron. There are many ways to prepare MgO thin film, including evaporation, pulsed laser deposition and MOCVD. It has been studied that doping can be used to enhance its emission capability and decrease its working potential of the thin film. In this paper, Ti-doped MgO thin films were deposited by magnetron sputtering method. Titanium metal and MgO ceramic were co-sputtered in oxygen containing argon ambient with DC and RF power source, respectively. XRD results show that the deposited film has the texture of (100) and (110) orientation. The ratio of Ti/Mg were consistent in XPS and EDS. SEM and AFM show that the film is polycrystalline. Electron multiplier device was assembled, and the secondary electron emission coefficient of the Ti-doped MgO film is greater than that of the undoped one, especially 36% higher at low primary electron energy of 200 eV which is meaningful to cesium atomic frequency standard.