Th3[Th6(OH)4O4(H2O)6](SO4)12(H2O)13: A Self-Assembled Microporous Open-Framework Thorium Sulfate

Jian Lin; Geng Bang Jin; L. Soderholm

doi:10.1021/acs.inorgchem.6b01762

Th₃[Th₆(OH)₄O₄(H₂O)₆](SO₄)₁₂(H₂O)₁₃: A Self-Assembled Microporous Open-Framework Thorium Sulfate

Jian Lin
, Geng Bang Jin
, L. Soderholm

Argonne National Laboratory

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

A neutral-framework thorium oxohydroxosulfate hydrate has been isolated from aqueous solution. This microporous structure, which self-assembles without a templating agent, is built from [Th₆(OH)₄O₄(H₂O)₆]¹²⁺ hexamers and thorium(IV) monomers linked through bridging sulfates. Solution conditions were chosen to enable an active competition between sulfate and hydroxide for thorium coordination. Synthetic requirements are discussed for this rare example of a thorium(IV) polynuclear complex containing mixed oxo-, hydroxo-, and sulfato-bridging moieties.

Original language	English
Pages (from-to)	10098-10101
Number of pages	4
Journal	Inorganic Chemistry
Volume	55
Issue number	20
DOIs	https://doi.org/10.1021/acs.inorgchem.6b01762
State	Published - 17 Oct 2016
Externally published	Yes

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title = "Th3[Th6(OH)4O4(H2O)6](SO4)12(H2O)13: A Self-Assembled Microporous Open-Framework Thorium Sulfate",

abstract = "A neutral-framework thorium oxohydroxosulfate hydrate has been isolated from aqueous solution. This microporous structure, which self-assembles without a templating agent, is built from [Th6(OH)4O4(H2O)6]12+ hexamers and thorium(IV) monomers linked through bridging sulfates. Solution conditions were chosen to enable an active competition between sulfate and hydroxide for thorium coordination. Synthetic requirements are discussed for this rare example of a thorium(IV) polynuclear complex containing mixed oxo-, hydroxo-, and sulfato-bridging moieties.",

author = "Jian Lin and Jin, \{Geng Bang\} and L. Soderholm",

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doi = "10.1021/acs.inorgchem.6b01762",

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T2 - A Self-Assembled Microporous Open-Framework Thorium Sulfate

AU - Lin, Jian

AU - Jin, Geng Bang

AU - Soderholm, L.

PY - 2016/10/17

Y1 - 2016/10/17

N2 - A neutral-framework thorium oxohydroxosulfate hydrate has been isolated from aqueous solution. This microporous structure, which self-assembles without a templating agent, is built from [Th6(OH)4O4(H2O)6]12+ hexamers and thorium(IV) monomers linked through bridging sulfates. Solution conditions were chosen to enable an active competition between sulfate and hydroxide for thorium coordination. Synthetic requirements are discussed for this rare example of a thorium(IV) polynuclear complex containing mixed oxo-, hydroxo-, and sulfato-bridging moieties.

AB - A neutral-framework thorium oxohydroxosulfate hydrate has been isolated from aqueous solution. This microporous structure, which self-assembles without a templating agent, is built from [Th6(OH)4O4(H2O)6]12+ hexamers and thorium(IV) monomers linked through bridging sulfates. Solution conditions were chosen to enable an active competition between sulfate and hydroxide for thorium coordination. Synthetic requirements are discussed for this rare example of a thorium(IV) polynuclear complex containing mixed oxo-, hydroxo-, and sulfato-bridging moieties.

UR - https://www.scopus.com/pages/publications/84992049148

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DO - 10.1021/acs.inorgchem.6b01762

M3 - 文章

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SN - 0020-1669

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SP - 10098

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 20

ER -

Th₃[Th₆(OH)₄O₄(H₂O)₆](SO₄)₁₂(H₂O)₁₃: A Self-Assembled Microporous Open-Framework Thorium Sulfate

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