Thermodynamic evaluation and optimization of the (LiCl + NaCl + KCl + MgCl                         2                          + CaCl                         2                          + CeCl                         3                         ) system

Guangxuan Lu; Christian Robelin; Patrice Chartrand; Maogang He; Kun Wang

doi:10.1016/j.fluid.2018.11.031

Thermodynamic evaluation and optimization of the (LiCl + NaCl + KCl + MgCl ₂ + CaCl ₂ + CeCl ₃ ) system

Guangxuan Lu
, Christian Robelin
, Patrice Chartrand
, Maogang He
, Kun Wang

School of Energy and Power Engineering

Xi'an Jiaotong University
École Polytechnique
Agency for Science, Technology and Research, Singapore

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

A complete critical evaluation of all available phase diagram and thermodynamic data has been performed for all condensed phases of the (LiCl + NaCl + KCl + MgCl ₂ + CaCl ₂ + CeCl ₃ ) system, and optimized model parameters have been found. The (LiCl + NaCl + KCl + MgCl ₂ + CaCl ₂ ) subsystem has been critically evaluated in a previous article. The model parameters obtained for the binary and ternary subsystems can be used to predict thermodynamic properties and phase equilibria for the multicomponent system. The Modified Quasichemical Model for short-range ordering was used for the molten salt phase, and the Compound Energy Formalism was used for the various solid solutions.

Original language	English
Pages (from-to)	83-97
Number of pages	15
Journal	Fluid Phase Equilibria
Volume	487
DOIs	https://doi.org/10.1016/j.fluid.2018.11.031
State	Published - 15 May 2019

Keywords

Cerium chloride
Molten chlorides
Thermodynamic database
Thermodynamic modeling

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10.1016/j.fluid.2018.11.031

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Lu, G., Robelin, C., Chartrand, P., He, M., & Wang, K. (2019). Thermodynamic evaluation and optimization of the (LiCl + NaCl + KCl + MgCl ₂ + CaCl ₂ + CeCl ₃ ) system Fluid Phase Equilibria, 487, 83-97. https://doi.org/10.1016/j.fluid.2018.11.031

Lu, Guangxuan ; Robelin, Christian ; Chartrand, Patrice et al. / Thermodynamic evaluation and optimization of the (LiCl + NaCl + KCl + MgCl ₂ + CaCl ₂ + CeCl ₃ ) system In: Fluid Phase Equilibria. 2019 ; Vol. 487. pp. 83-97.

@article{ceeb706172404f9b86e4e07712092782,

title = " Thermodynamic evaluation and optimization of the (LiCl + NaCl + KCl + MgCl 2 + CaCl 2 + CeCl 3 ) system ",

abstract = " A complete critical evaluation of all available phase diagram and thermodynamic data has been performed for all condensed phases of the (LiCl + NaCl + KCl + MgCl 2 + CaCl 2 + CeCl 3 ) system, and optimized model parameters have been found. The (LiCl + NaCl + KCl + MgCl 2 + CaCl 2 ) subsystem has been critically evaluated in a previous article. The model parameters obtained for the binary and ternary subsystems can be used to predict thermodynamic properties and phase equilibria for the multicomponent system. The Modified Quasichemical Model for short-range ordering was used for the molten salt phase, and the Compound Energy Formalism was used for the various solid solutions.",

keywords = "Cerium chloride, Molten chlorides, Thermodynamic database, Thermodynamic modeling",

author = "Guangxuan Lu and Christian Robelin and Patrice Chartrand and Maogang He and Kun Wang",

note = "Publisher Copyright: {\textcopyright} 2018 Elsevier B.V.",

year = "2019",

month = may,

day = "15",

doi = "10.1016/j.fluid.2018.11.031",

language = "英语",

volume = "487",

pages = "83--97",

journal = "Fluid Phase Equilibria",

issn = "0378-3812",

publisher = "Elsevier B.V.",

}

Lu, G, Robelin, C, Chartrand, P, He, M & Wang, K 2019, ' Thermodynamic evaluation and optimization of the (LiCl + NaCl + KCl + MgCl ₂ + CaCl ₂ + CeCl ₃ ) system ', Fluid Phase Equilibria, vol. 487, pp. 83-97. https://doi.org/10.1016/j.fluid.2018.11.031

Thermodynamic evaluation and optimization of the (LiCl + NaCl + KCl + MgCl ₂ + CaCl ₂ + CeCl ₃ ) system . / Lu, Guangxuan; Robelin, Christian; Chartrand, Patrice et al.
In: Fluid Phase Equilibria, Vol. 487, 15.05.2019, p. 83-97.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Thermodynamic evaluation and optimization of the (LiCl + NaCl + KCl + MgCl 2 + CaCl 2 + CeCl 3 ) system

AU - Lu, Guangxuan

AU - Robelin, Christian

AU - Chartrand, Patrice

AU - He, Maogang

AU - Wang, Kun

PY - 2019/5/15

Y1 - 2019/5/15

N2 - A complete critical evaluation of all available phase diagram and thermodynamic data has been performed for all condensed phases of the (LiCl + NaCl + KCl + MgCl 2 + CaCl 2 + CeCl 3 ) system, and optimized model parameters have been found. The (LiCl + NaCl + KCl + MgCl 2 + CaCl 2 ) subsystem has been critically evaluated in a previous article. The model parameters obtained for the binary and ternary subsystems can be used to predict thermodynamic properties and phase equilibria for the multicomponent system. The Modified Quasichemical Model for short-range ordering was used for the molten salt phase, and the Compound Energy Formalism was used for the various solid solutions.

AB - A complete critical evaluation of all available phase diagram and thermodynamic data has been performed for all condensed phases of the (LiCl + NaCl + KCl + MgCl 2 + CaCl 2 + CeCl 3 ) system, and optimized model parameters have been found. The (LiCl + NaCl + KCl + MgCl 2 + CaCl 2 ) subsystem has been critically evaluated in a previous article. The model parameters obtained for the binary and ternary subsystems can be used to predict thermodynamic properties and phase equilibria for the multicomponent system. The Modified Quasichemical Model for short-range ordering was used for the molten salt phase, and the Compound Energy Formalism was used for the various solid solutions.

KW - Cerium chloride

KW - Molten chlorides

KW - Thermodynamic database

KW - Thermodynamic modeling

UR - https://www.scopus.com/pages/publications/85060691850

U2 - 10.1016/j.fluid.2018.11.031

DO - 10.1016/j.fluid.2018.11.031

M3 - 文章

AN - SCOPUS:85060691850

SN - 0378-3812

VL - 487

SP - 83

EP - 97

JO - Fluid Phase Equilibria

JF - Fluid Phase Equilibria

ER -

Lu G, Robelin C, Chartrand P, He M, Wang K. Thermodynamic evaluation and optimization of the (LiCl + NaCl + KCl + MgCl ₂ + CaCl ₂ + CeCl ₃ ) system Fluid Phase Equilibria. 2019 May 15;487:83-97. doi: 10.1016/j.fluid.2018.11.031

Thermodynamic evaluation and optimization of the (LiCl + NaCl + KCl + MgCl ₂ + CaCl ₂ + CeCl ₃ ) system

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Keywords

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