Thermal Diffusivity and Speed of Sound of Saturated Pentane from Light Scattering

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Abstract

Transport and thermodynamic properties of pentane are necessary for the design and verification of reactors in pentane isomerization and degradation processes. However, there are few experimental data of these properties, especially in the hightemperature region. In thiswork, the thermal diffusivity and the sound speed of pentane have measured by dynamic light scattering and Brillouin light scattering, respectively. Pentane has been investigated under saturated conditions over a wide temperature range, from about 300 K up to the liquid-vapor critical point. It is estimated that: the standard uncertainty of temperature is u(T ) = 0.01K for the hydrodynamic region and u(T ) = 0.026K for the critical region; the relative expanded uncertainty in the thermal diffusivity is Ur(a) = 0.03 and the relative expanded uncertainty in the speed of sound is Ur(cs) = 0.005 with a coverage factor of k = 2. The thermal diffusivity and the sound-speed experimental data are also represented as functions of temperature. Finally, the results are discussed in detail in comparison with literature results and various prediction methods.

Original languageEnglish
Pages (from-to)1450-1464
Number of pages15
JournalInternational Journal of Thermophysics
Volume35
Issue number8
DOIs
StatePublished - 16 Oct 2014

Keywords

  • Light scattering
  • Pentane
  • Speed of sound
  • Thermal diffusivity

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