Thermal Decomposition of Photocurable Energetic APNIMMO Polymer

Weitao Yang; Rui Hu; Manman Li; Minghui Xu; Zhiwei Yang; Lingjie Meng

doi:10.1002/prep.202100239

Thermal Decomposition of Photocurable Energetic APNIMMO Polymer

Weitao Yang
, Rui Hu
, Manman Li
, Minghui Xu
, Zhiwei Yang
, Lingjie Meng

School of Chemistry

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Photocurable energetic polymer contains energetic groups (explosophores) and provides fast curable property for 3D printed propellants. Acrylate-terminated poly-3-nitratomethyl-3-methyloxetane (APNIMMO) was prepared for the stereolithography (SLA) printing. This work outlines the thermal decomposition process of APNIMMO. The thermal behaviour and decomposition kinetics were investigated by means of the non-isothermal DSC (differential scanning calorimetry) techniques. The Arrhenius parameters were studied by different isoconversional Kissinger method. Additionally, simultaneous TG-DSC-FTIR-MS were employed to corroborate the thermal analysis results. The obtained results from the different techniques are presented and discussed.

Original language	English
Pages (from-to)	1767-1771
Number of pages	5
Journal	Propellants, Explosives, Pyrotechnics
Volume	46
Issue number	12
DOIs	https://doi.org/10.1002/prep.202100239
State	Published - Dec 2021

Keywords

APNIMMO
Decomposition kinetics
Energetic polymer
Thermal behaviors

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10.1002/prep.202100239

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title = "Thermal Decomposition of Photocurable Energetic APNIMMO Polymer",

abstract = "Photocurable energetic polymer contains energetic groups (explosophores) and provides fast curable property for 3D printed propellants. Acrylate-terminated poly-3-nitratomethyl-3-methyloxetane (APNIMMO) was prepared for the stereolithography (SLA) printing. This work outlines the thermal decomposition process of APNIMMO. The thermal behaviour and decomposition kinetics were investigated by means of the non-isothermal DSC (differential scanning calorimetry) techniques. The Arrhenius parameters were studied by different isoconversional Kissinger method. Additionally, simultaneous TG-DSC-FTIR-MS were employed to corroborate the thermal analysis results. The obtained results from the different techniques are presented and discussed.",

keywords = "APNIMMO, Decomposition kinetics, Energetic polymer, Thermal behaviors",

author = "Weitao Yang and Rui Hu and Manman Li and Minghui Xu and Zhiwei Yang and Lingjie Meng",

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year = "2021",

month = dec,

doi = "10.1002/prep.202100239",

language = "英语",

volume = "46",

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T1 - Thermal Decomposition of Photocurable Energetic APNIMMO Polymer

AU - Yang, Weitao

AU - Hu, Rui

AU - Li, Manman

AU - Xu, Minghui

AU - Yang, Zhiwei

AU - Meng, Lingjie

PY - 2021/12

Y1 - 2021/12

N2 - Photocurable energetic polymer contains energetic groups (explosophores) and provides fast curable property for 3D printed propellants. Acrylate-terminated poly-3-nitratomethyl-3-methyloxetane (APNIMMO) was prepared for the stereolithography (SLA) printing. This work outlines the thermal decomposition process of APNIMMO. The thermal behaviour and decomposition kinetics were investigated by means of the non-isothermal DSC (differential scanning calorimetry) techniques. The Arrhenius parameters were studied by different isoconversional Kissinger method. Additionally, simultaneous TG-DSC-FTIR-MS were employed to corroborate the thermal analysis results. The obtained results from the different techniques are presented and discussed.

AB - Photocurable energetic polymer contains energetic groups (explosophores) and provides fast curable property for 3D printed propellants. Acrylate-terminated poly-3-nitratomethyl-3-methyloxetane (APNIMMO) was prepared for the stereolithography (SLA) printing. This work outlines the thermal decomposition process of APNIMMO. The thermal behaviour and decomposition kinetics were investigated by means of the non-isothermal DSC (differential scanning calorimetry) techniques. The Arrhenius parameters were studied by different isoconversional Kissinger method. Additionally, simultaneous TG-DSC-FTIR-MS were employed to corroborate the thermal analysis results. The obtained results from the different techniques are presented and discussed.

KW - APNIMMO

KW - Decomposition kinetics

KW - Energetic polymer

KW - Thermal behaviors

UR - https://www.scopus.com/pages/publications/85118548130

U2 - 10.1002/prep.202100239

DO - 10.1002/prep.202100239

M3 - 文章

AN - SCOPUS:85118548130

SN - 0721-3115

VL - 46

SP - 1767

EP - 1771

JO - Propellants, Explosives, Pyrotechnics

JF - Propellants, Explosives, Pyrotechnics

IS - 12

ER -

Thermal Decomposition of Photocurable Energetic APNIMMO Polymer

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Keywords

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