The Heavy Particulate Matter Pollution During the COVID-19 Lockdown Period in the Guanzhong Basin, China

Nationwide restrictions on human activities (lockdown) in China since 23 January 2020, to control the 2019 novel coronavirus disease pandemic (COVID-19), has provided an opportunity to evaluate the effect of emission mitigation on particulate matter (PM) pollution. The WRF-Chem simulations of persistent heavy PM pollution episodes from 20 January to 14 February 2020, in the Guanzhong Basin (GZB), northwest China, reveal that large-scale emission reduction of primary pollutants has not substantially improved the air quality during the COVID-19 lockdown period. Simultaneous reduction of primary precursors during the lockdown period only decreases the near-surface PM_2.5 mass concentration by 11.6% (12.6 μg m⁻³), but increases ozone (O₃) concentration by 9.2% (5.5 μg m⁻³) in the GZB. The primary organic aerosol and nitrate are the major contributor to the decreased PM_2.5 in the GZB, with the reduction of 28.0% and 21.8%, respectively, followed by EC (10.1%) and ammonium (7.2%). The increased atmospheric oxidizing capacity by the O₃ enhancement facilitates the secondary aerosol (SA) formation in the GZB, increasing secondary organic aerosol and sulphate by 6.5% and 3.3%, respectively. Furthermore, sensitivity experiments suggest that combined emission reduction of NO_X and VOCs following the ratio of 1:1 is conducive to lowering the wintertime SA and O₃ concentration and further alleviating the PM pollution in the GZB.