The effects of alumina morphology and Pt electron property on reversible hydrogenation and dehydrogenation of dibenzyltoluene as a liquid organic hydrogen carrier

The morphologies and the electron property of catalysts play the very important roles in the hydrogenation and dehydrogenation of liquid organic hydrogen carriers (LOHCs) such as dibenzyltoluene (DBT). The different morphologies and pore structures of γ-Al₂O₃ and Mo_xC doped γ-Al₂O₃ were synthesized as the supports for Pt catalysts. After analyzing of various characterizations and catalytic testing, it was found that the large surface area and the mesoporous structure of catalysts are beneficial to both DBT hydrogenation and perhydro-dibenzyltoluene (H18-DBT) dehydrogenation. The doping of Mo_xC promoted the formation of the smaller Pt nanoparticles and increased Pt dispersion. The forming Pt–Mo structure is beneficial to hydrogen spillover which suppress the formation of by-product. The high Pt dispersion of 0.1 wt% Mo_xC doped Pt/Al₂O₃ catalyst plays the positive roles in increasing H18-DBT dehydrogenation activity.