The Chemical Potential of Vacancies in Metal Crystal

Sun Jun; W. R. Tyson

The Chemical Potential of Vacancies in Metal Crystal

Sun Jun
, W. R. Tyson

School of Materials Science and Engineering

Natural Resources Canada

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

In this paper, a concept, the chemical potential of vacancies in metal crystals, has been derived from the partial mole free energy of vacancies, based on a model of an atom-vacancy binary solution. For a pure metal crystal containing the mole concentration of vacancies, C_y and it's value in thermal equilibrium, C_o, at temperature T, the chemical potential can be expressed respectively as: μ(C_v) = RT[1 + 1n(C_v/C_o)] and μ(C_o) = RT The second term in μ_v (C_v) is the chemical potential of the vacancies referred to the standard-state concentration given by J. P. Hirth^[1] and first term is the standard-state one presented.

Original language	English
Pages (from-to)	301-303
Number of pages	3
Journal	Xiyou Jinshu Cailiao Yu Gongcheng/Rare Metal Materials and Engineering
Volume	29
Issue number	5
State	Published - Oct 2000

Keywords

Atom-vacancy binary solution
Chemical potential
Metal crystal

Cite this

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title = "The Chemical Potential of Vacancies in Metal Crystal",

abstract = "In this paper, a concept, the chemical potential of vacancies in metal crystals, has been derived from the partial mole free energy of vacancies, based on a model of an atom-vacancy binary solution. For a pure metal crystal containing the mole concentration of vacancies, Cy and it's value in thermal equilibrium, Co, at temperature T, the chemical potential can be expressed respectively as: μ(Cv) = RT[1 + 1n(Cv/Co)] and μ(Co) = RT The second term in μv (Cv) is the chemical potential of the vacancies referred to the standard-state concentration given by J. P. Hirth[1] and first term is the standard-state one presented.",

keywords = "Atom-vacancy binary solution, Chemical potential, Metal crystal",

author = "Sun Jun and Tyson, \{W. R.\}",

year = "2000",

month = oct,

language = "英语",

volume = "29",

pages = "301--303",

journal = "Xiyou Jinshu Cailiao Yu Gongcheng/Rare Metal Materials and Engineering",

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T1 - The Chemical Potential of Vacancies in Metal Crystal

AU - Jun, Sun

AU - Tyson, W. R.

PY - 2000/10

Y1 - 2000/10

N2 - In this paper, a concept, the chemical potential of vacancies in metal crystals, has been derived from the partial mole free energy of vacancies, based on a model of an atom-vacancy binary solution. For a pure metal crystal containing the mole concentration of vacancies, Cy and it's value in thermal equilibrium, Co, at temperature T, the chemical potential can be expressed respectively as: μ(Cv) = RT[1 + 1n(Cv/Co)] and μ(Co) = RT The second term in μv (Cv) is the chemical potential of the vacancies referred to the standard-state concentration given by J. P. Hirth[1] and first term is the standard-state one presented.

AB - In this paper, a concept, the chemical potential of vacancies in metal crystals, has been derived from the partial mole free energy of vacancies, based on a model of an atom-vacancy binary solution. For a pure metal crystal containing the mole concentration of vacancies, Cy and it's value in thermal equilibrium, Co, at temperature T, the chemical potential can be expressed respectively as: μ(Cv) = RT[1 + 1n(Cv/Co)] and μ(Co) = RT The second term in μv (Cv) is the chemical potential of the vacancies referred to the standard-state concentration given by J. P. Hirth[1] and first term is the standard-state one presented.

KW - Atom-vacancy binary solution

KW - Chemical potential

KW - Metal crystal

UR - https://www.scopus.com/pages/publications/0348003185

M3 - 文章

AN - SCOPUS:0348003185

SN - 1002-185X

VL - 29

SP - 301

EP - 303

JO - Xiyou Jinshu Cailiao Yu Gongcheng/Rare Metal Materials and Engineering

JF - Xiyou Jinshu Cailiao Yu Gongcheng/Rare Metal Materials and Engineering

IS - 5

ER -

The Chemical Potential of Vacancies in Metal Crystal

Abstract

Keywords

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