Terbium-fluorido cluster: An energy cage for photoluminescence

Bo Kai Ling; Junhao Li; Yuan Qi Zhai; Hung Kai Hsu; Yi Tsu Chan; Wei Peng Chen; Tian Han; Yan Zhen Zheng

doi:10.1039/d0cc02898c

Terbium-fluorido cluster: An energy cage for photoluminescence

Bo Kai Ling
, Junhao Li
, Yuan Qi Zhai
, Hung Kai Hsu
, Yi Tsu Chan
, Wei Peng Chen
, Tian Han
, Yan Zhen Zheng

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

We report here that energy migration during luminescence can be extremely minimized by caging the fluorescent centers in a molecular cluster of [Tb6(μ3-F)8(piv)10(Hpiv)4DMF]·xDMF·yH2O 1. Experimental and theoretical simulations reveal that bonding terbium with fluoride is the key to reducing the non-radiative multi-phonon relaxation processes, which is disparate to the common hydroxy-based lanthanide clusters.

Original language	English
Pages (from-to)	9130-9133
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	64
DOIs	https://doi.org/10.1039/d0cc02898c
State	Published - 18 Aug 2020

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title = "Terbium-fluorido cluster: An energy cage for photoluminescence",

abstract = "We report here that energy migration during luminescence can be extremely minimized by caging the fluorescent centers in a molecular cluster of [Tb6(μ3-F)8(piv)10(Hpiv)4DMF]·xDMF·yH2O 1. Experimental and theoretical simulations reveal that bonding terbium with fluoride is the key to reducing the non-radiative multi-phonon relaxation processes, which is disparate to the common hydroxy-based lanthanide clusters.",

author = "Ling, \{Bo Kai\} and Junhao Li and Zhai, \{Yuan Qi\} and Hsu, \{Hung Kai\} and Chan, \{Yi Tsu\} and Chen, \{Wei Peng\} and Tian Han and Zheng, \{Yan Zhen\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2020",

month = aug,

day = "18",

doi = "10.1039/d0cc02898c",

language = "英语",

volume = "56",

pages = "9130--9133",

journal = "Chemical Communications",

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TY - JOUR

T1 - Terbium-fluorido cluster

T2 - An energy cage for photoluminescence

AU - Ling, Bo Kai

AU - Li, Junhao

AU - Zhai, Yuan Qi

AU - Hsu, Hung Kai

AU - Chan, Yi Tsu

AU - Chen, Wei Peng

AU - Han, Tian

AU - Zheng, Yan Zhen

PY - 2020/8/18

Y1 - 2020/8/18

N2 - We report here that energy migration during luminescence can be extremely minimized by caging the fluorescent centers in a molecular cluster of [Tb6(μ3-F)8(piv)10(Hpiv)4DMF]·xDMF·yH2O 1. Experimental and theoretical simulations reveal that bonding terbium with fluoride is the key to reducing the non-radiative multi-phonon relaxation processes, which is disparate to the common hydroxy-based lanthanide clusters.

AB - We report here that energy migration during luminescence can be extremely minimized by caging the fluorescent centers in a molecular cluster of [Tb6(μ3-F)8(piv)10(Hpiv)4DMF]·xDMF·yH2O 1. Experimental and theoretical simulations reveal that bonding terbium with fluoride is the key to reducing the non-radiative multi-phonon relaxation processes, which is disparate to the common hydroxy-based lanthanide clusters.

UR - https://www.scopus.com/pages/publications/85089358799

U2 - 10.1039/d0cc02898c

DO - 10.1039/d0cc02898c

M3 - 文章

C2 - 32643731

AN - SCOPUS:85089358799

SN - 1359-7345

VL - 56

SP - 9130

EP - 9133

JO - Chemical Communications

JF - Chemical Communications

IS - 64

ER -

Terbium-fluorido cluster: An energy cage for photoluminescence

Abstract

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