Abstract
Thermal emission is the process by which all objects at nonzero temperatures emit light and is well described by the Planck, Kirchhoff, and Stefan-Boltzmann laws. For most solids, the thermally emitted power increases monotonically with temperature in a one-to-one relationship that enables applications such as infrared imaging and noncontact thermometry. Here, we demonstrated ultrathin thermal emitters that violate this one-to-one relationship via the use of samarium nickel oxide (SmNiO3), a strongly correlated quantum material that undergoes a fully reversible, temperaturedriven solid-state phase transition. The smooth and hysteresis-free nature of this unique insulator-to-metal phase transition enabled us to engineer the temperature dependence of emissivity to precisely cancel out the intrinsic blackbody profile described by the Stefan- Boltzmann law, for both heating and cooling. Our design results in temperature-independent thermally emitted power within the long-wave atmospheric transparency window (wavelengths of 8 to 14 μm), across a broad temperature range of ~30 °C, centered around ~120 °C. The ability to decouple temperature and thermal emission opens a gateway for controlling the visibility of objects to infrared cameras and, more broadly, opportunities for quantum materials in controlling heat transfer.
| Original language | English |
|---|---|
| Pages (from-to) | 26402-26406 |
| Number of pages | 5 |
| Journal | Proceedings of the National Academy of Sciences of the United States of America |
| Volume | 116 |
| Issue number | 52 |
| DOIs | |
| State | Published - 26 Dec 2019 |
| Externally published | Yes |
Keywords
- Heat transfer
- Phase transition
- Quantum materials
- Thermal emission
- Thermal radiation