Synthesis of polyacene quinone radical polymers with controllable conductivity and their smart electrorheological behavior

Baoxiang Wang; Lili Ma; Chuncheng Hao; Qingquan Lei

doi:10.1016/j.synthmet.2013.09.003

Synthesis of polyacene quinone radical polymers with controllable conductivity and their smart electrorheological behavior

Baoxiang Wang
, Lili Ma
, Chuncheng Hao
, Qingquan Lei

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Polyacene quinone radical (PAQR) polymers were synthesized by the step-growth condensation of aromatic hydrocarbon derivatives reacting with pyromellitic anhydride via a solvothermal method. The morphology and structures of PAQRs with varied polymerization processes were confirmed by the analysis of X-ray, IR, SEM and TG measurement. The effects of different aromatic hydrocarbons on the synthesis and morphology of PAQR polymers were investigated and then utilized as an electrorheological (ER) material by dispersion in silicone oil. The ER performances are investigated as a function of electric field strength by using a rheometer and the relationship between the conductivity and electrorheological (ER) properties of different polyacene quinone radical (PAQR) polymers were discussed.

Original language	English
Pages (from-to)	28-32
Number of pages	5
Journal	Synthetic Metals
Volume	182
DOIs	https://doi.org/10.1016/j.synthmet.2013.09.003
State	Published - 2013
Externally published	Yes

Keywords

Conductive polymer
Electrorheological fluid
PAQR polymer
Solvothermal method

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10.1016/j.synthmet.2013.09.003

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title = "Synthesis of polyacene quinone radical polymers with controllable conductivity and their smart electrorheological behavior",

abstract = "Polyacene quinone radical (PAQR) polymers were synthesized by the step-growth condensation of aromatic hydrocarbon derivatives reacting with pyromellitic anhydride via a solvothermal method. The morphology and structures of PAQRs with varied polymerization processes were confirmed by the analysis of X-ray, IR, SEM and TG measurement. The effects of different aromatic hydrocarbons on the synthesis and morphology of PAQR polymers were investigated and then utilized as an electrorheological (ER) material by dispersion in silicone oil. The ER performances are investigated as a function of electric field strength by using a rheometer and the relationship between the conductivity and electrorheological (ER) properties of different polyacene quinone radical (PAQR) polymers were discussed.",

keywords = "Conductive polymer, Electrorheological fluid, PAQR polymer, Solvothermal method",

author = "Baoxiang Wang and Lili Ma and Chuncheng Hao and Qingquan Lei",

year = "2013",

doi = "10.1016/j.synthmet.2013.09.003",

language = "英语",

volume = "182",

pages = "28--32",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Synthesis of polyacene quinone radical polymers with controllable conductivity and their smart electrorheological behavior

AU - Wang, Baoxiang

AU - Ma, Lili

AU - Hao, Chuncheng

AU - Lei, Qingquan

PY - 2013

Y1 - 2013

N2 - Polyacene quinone radical (PAQR) polymers were synthesized by the step-growth condensation of aromatic hydrocarbon derivatives reacting with pyromellitic anhydride via a solvothermal method. The morphology and structures of PAQRs with varied polymerization processes were confirmed by the analysis of X-ray, IR, SEM and TG measurement. The effects of different aromatic hydrocarbons on the synthesis and morphology of PAQR polymers were investigated and then utilized as an electrorheological (ER) material by dispersion in silicone oil. The ER performances are investigated as a function of electric field strength by using a rheometer and the relationship between the conductivity and electrorheological (ER) properties of different polyacene quinone radical (PAQR) polymers were discussed.

AB - Polyacene quinone radical (PAQR) polymers were synthesized by the step-growth condensation of aromatic hydrocarbon derivatives reacting with pyromellitic anhydride via a solvothermal method. The morphology and structures of PAQRs with varied polymerization processes were confirmed by the analysis of X-ray, IR, SEM and TG measurement. The effects of different aromatic hydrocarbons on the synthesis and morphology of PAQR polymers were investigated and then utilized as an electrorheological (ER) material by dispersion in silicone oil. The ER performances are investigated as a function of electric field strength by using a rheometer and the relationship between the conductivity and electrorheological (ER) properties of different polyacene quinone radical (PAQR) polymers were discussed.

KW - Conductive polymer

KW - Electrorheological fluid

KW - PAQR polymer

KW - Solvothermal method

UR - https://www.scopus.com/pages/publications/84885160536

U2 - 10.1016/j.synthmet.2013.09.003

DO - 10.1016/j.synthmet.2013.09.003

M3 - 文章

AN - SCOPUS:84885160536

SN - 0379-6779

VL - 182

SP - 28

EP - 32

JO - Synthetic Metals

JF - Synthetic Metals

ER -

Synthesis of polyacene quinone radical polymers with controllable conductivity and their smart electrorheological behavior

Abstract

Keywords

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