Synthesis of nanosized Al-HMS and its application in deep oxidation of benzene

Wei Zhao; Jinjun Li; Chi He; Lina Wang; Jinlong Chu; Jinkui Qu; Tao Qi; Zhengping Hao

doi:10.1016/j.cattod.2010.06.006

Synthesis of nanosized Al-HMS and its application in deep oxidation of benzene

Wei Zhao
, Jinjun Li
, Chi He
, Lina Wang
, Jinlong Chu
, Jinkui Qu
, Tao Qi
, Zhengping Hao

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

High quality nanosize Al-HMS was successfully synthesized using ethanol as the co-solvent. Pd atoms could be highly dispersed on this nanosize support with ordered size of ca.12 nm. TEM studies revealed that support size could influence Pd dispersion behaviors greatly. Besides, frame Al of support also played some positive role on the catalytic activity of Pd-loaded catalyst. The complete conversion of benzene could be got at 200 °C on this nanosize Pd/Al-HMS catalyst loaded only 0.9 wt% Pd under high gas hourly space velocity of ca.100 000 h^-1.

Original language	English
Pages (from-to)	427-431
Number of pages	5
Journal	Catalysis Today
Volume	158
Issue number	3-4
DOIs	https://doi.org/10.1016/j.cattod.2010.06.006
State	Published - 22 Dec 2010
Externally published	Yes

Keywords

Al-HMS
Benzene
Catalytic combustion
Nanostructures
Pd

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10.1016/j.cattod.2010.06.006

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title = "Synthesis of nanosized Al-HMS and its application in deep oxidation of benzene",

abstract = "High quality nanosize Al-HMS was successfully synthesized using ethanol as the co-solvent. Pd atoms could be highly dispersed on this nanosize support with ordered size of ca.12 nm. TEM studies revealed that support size could influence Pd dispersion behaviors greatly. Besides, frame Al of support also played some positive role on the catalytic activity of Pd-loaded catalyst. The complete conversion of benzene could be got at 200 °C on this nanosize Pd/Al-HMS catalyst loaded only 0.9 wt\% Pd under high gas hourly space velocity of ca.100 000 h-1.",

keywords = "Al-HMS, Benzene, Catalytic combustion, Nanostructures, Pd",

author = "Wei Zhao and Jinjun Li and Chi He and Lina Wang and Jinlong Chu and Jinkui Qu and Tao Qi and Zhengping Hao",

year = "2010",

month = dec,

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doi = "10.1016/j.cattod.2010.06.006",

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T1 - Synthesis of nanosized Al-HMS and its application in deep oxidation of benzene

AU - Zhao, Wei

AU - Li, Jinjun

AU - He, Chi

AU - Wang, Lina

AU - Chu, Jinlong

AU - Qu, Jinkui

AU - Qi, Tao

AU - Hao, Zhengping

PY - 2010/12/22

Y1 - 2010/12/22

N2 - High quality nanosize Al-HMS was successfully synthesized using ethanol as the co-solvent. Pd atoms could be highly dispersed on this nanosize support with ordered size of ca.12 nm. TEM studies revealed that support size could influence Pd dispersion behaviors greatly. Besides, frame Al of support also played some positive role on the catalytic activity of Pd-loaded catalyst. The complete conversion of benzene could be got at 200 °C on this nanosize Pd/Al-HMS catalyst loaded only 0.9 wt% Pd under high gas hourly space velocity of ca.100 000 h-1.

AB - High quality nanosize Al-HMS was successfully synthesized using ethanol as the co-solvent. Pd atoms could be highly dispersed on this nanosize support with ordered size of ca.12 nm. TEM studies revealed that support size could influence Pd dispersion behaviors greatly. Besides, frame Al of support also played some positive role on the catalytic activity of Pd-loaded catalyst. The complete conversion of benzene could be got at 200 °C on this nanosize Pd/Al-HMS catalyst loaded only 0.9 wt% Pd under high gas hourly space velocity of ca.100 000 h-1.

KW - Al-HMS

KW - Benzene

KW - Catalytic combustion

KW - Nanostructures

KW - Pd

UR - https://www.scopus.com/pages/publications/78649726285

U2 - 10.1016/j.cattod.2010.06.006

DO - 10.1016/j.cattod.2010.06.006

M3 - 文章

AN - SCOPUS:78649726285

SN - 0920-5861

VL - 158

SP - 427

EP - 431

JO - Catalysis Today

JF - Catalysis Today

IS - 3-4

ER -

Synthesis of nanosized Al-HMS and its application in deep oxidation of benzene

Abstract

Keywords

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