Synthesis of fully bio-based polyamides with tunable properties by employing itaconic acid

Zhao Wang; Tao Wei; Xiao Xue; Miaomiao He; Jiajia Xue; Meng Song; Sizhu Wu; Hailan Kang; Liqun Zhang; Qingxiu Jia

doi:10.1016/j.polymer.2014.07.034

Synthesis of fully bio-based polyamides with tunable properties by employing itaconic acid

Zhao Wang
, Tao Wei
, Xiao Xue
, Miaomiao He
, Jiajia Xue
, Meng Song
, Sizhu Wu
, Hailan Kang
, Liqun Zhang
, Qingxiu Jia

Research output: Contribution to journal › Article › peer-review

75 Scopus citations

Abstract

A class of bio-based aliphatic polyamides (BDIS) was synthesized by melting copolycondensation from four biomass monomers: originated (SA), itaconic acid (IA), 1, 10-decanediamine (DD), and 1, 4-butanediamine (BD). IA was introduced into the system in order to adjust the chemical structure and the aggregation structures of the BDIS polyamide. Thus, some new polyamides with tunable properties were obtained, such as semi-crystalline polyamide with relatively low melting point, glassy polyamide with excellent toughness, and even rubbery polyamide after hydration. Some of the BDIS can be well melting spinned into fibers with comparable strength as polyamide-6. The BDIS with 100% itaconic acid can even be dissolved in ethanol, which makes it possibly be used by coating and dipping methods. In vitro cytotoxicity tests showed that these polyamides are nontoxic towards mouse fibroblasts and have great potential in biomedical applications.

Original language	English
Pages (from-to)	4846-4856
Number of pages	11
Journal	Polymer
Volume	55
Issue number	19
DOIs	https://doi.org/10.1016/j.polymer.2014.07.034
State	Published - 15 Sep 2014
Externally published	Yes

Keywords

Aliphatic polyamide
Bio-based
Itaconic acid

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10.1016/j.polymer.2014.07.034

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title = "Synthesis of fully bio-based polyamides with tunable properties by employing itaconic acid",

abstract = "A class of bio-based aliphatic polyamides (BDIS) was synthesized by melting copolycondensation from four biomass monomers: originated (SA), itaconic acid (IA), 1, 10-decanediamine (DD), and 1, 4-butanediamine (BD). IA was introduced into the system in order to adjust the chemical structure and the aggregation structures of the BDIS polyamide. Thus, some new polyamides with tunable properties were obtained, such as semi-crystalline polyamide with relatively low melting point, glassy polyamide with excellent toughness, and even rubbery polyamide after hydration. Some of the BDIS can be well melting spinned into fibers with comparable strength as polyamide-6. The BDIS with 100\% itaconic acid can even be dissolved in ethanol, which makes it possibly be used by coating and dipping methods. In vitro cytotoxicity tests showed that these polyamides are nontoxic towards mouse fibroblasts and have great potential in biomedical applications.",

keywords = "Aliphatic polyamide, Bio-based, Itaconic acid",

author = "Zhao Wang and Tao Wei and Xiao Xue and Miaomiao He and Jiajia Xue and Meng Song and Sizhu Wu and Hailan Kang and Liqun Zhang and Qingxiu Jia",

year = "2014",

month = sep,

day = "15",

doi = "10.1016/j.polymer.2014.07.034",

language = "英语",

volume = "55",

pages = "4846--4856",

journal = "Polymer",

issn = "0032-3861",

publisher = "Elsevier B.V.",

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}

TY - JOUR

T1 - Synthesis of fully bio-based polyamides with tunable properties by employing itaconic acid

AU - Wang, Zhao

AU - Wei, Tao

AU - Xue, Xiao

AU - He, Miaomiao

AU - Xue, Jiajia

AU - Song, Meng

AU - Wu, Sizhu

AU - Kang, Hailan

AU - Zhang, Liqun

AU - Jia, Qingxiu

PY - 2014/9/15

Y1 - 2014/9/15

N2 - A class of bio-based aliphatic polyamides (BDIS) was synthesized by melting copolycondensation from four biomass monomers: originated (SA), itaconic acid (IA), 1, 10-decanediamine (DD), and 1, 4-butanediamine (BD). IA was introduced into the system in order to adjust the chemical structure and the aggregation structures of the BDIS polyamide. Thus, some new polyamides with tunable properties were obtained, such as semi-crystalline polyamide with relatively low melting point, glassy polyamide with excellent toughness, and even rubbery polyamide after hydration. Some of the BDIS can be well melting spinned into fibers with comparable strength as polyamide-6. The BDIS with 100% itaconic acid can even be dissolved in ethanol, which makes it possibly be used by coating and dipping methods. In vitro cytotoxicity tests showed that these polyamides are nontoxic towards mouse fibroblasts and have great potential in biomedical applications.

AB - A class of bio-based aliphatic polyamides (BDIS) was synthesized by melting copolycondensation from four biomass monomers: originated (SA), itaconic acid (IA), 1, 10-decanediamine (DD), and 1, 4-butanediamine (BD). IA was introduced into the system in order to adjust the chemical structure and the aggregation structures of the BDIS polyamide. Thus, some new polyamides with tunable properties were obtained, such as semi-crystalline polyamide with relatively low melting point, glassy polyamide with excellent toughness, and even rubbery polyamide after hydration. Some of the BDIS can be well melting spinned into fibers with comparable strength as polyamide-6. The BDIS with 100% itaconic acid can even be dissolved in ethanol, which makes it possibly be used by coating and dipping methods. In vitro cytotoxicity tests showed that these polyamides are nontoxic towards mouse fibroblasts and have great potential in biomedical applications.

KW - Aliphatic polyamide

KW - Bio-based

KW - Itaconic acid

UR - https://www.scopus.com/pages/publications/84908142648

U2 - 10.1016/j.polymer.2014.07.034

DO - 10.1016/j.polymer.2014.07.034

M3 - 文章

AN - SCOPUS:84908142648

SN - 0032-3861

VL - 55

SP - 4846

EP - 4856

JO - Polymer

JF - Polymer

IS - 19

ER -

Synthesis of fully bio-based polyamides with tunable properties by employing itaconic acid

Abstract

Keywords

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