Synthesis of a rare 3D copper cyanide compound based on 3-(5-(pyridin-4-yl)-1H-1,2,4-triazol-3-yl)pyridine via the transformation of acetonitrile to inorganic cyanide

Linyan Yang; Liangliang Xin; Jinlei Tian; Peiyao Du; Xiaohua Wei; Shengyun Liao; Yanping Zhang; Rui Lv; Wen Gu; Xin Liu

doi:10.1016/j.molstruc.2014.01.090

Synthesis of a rare 3D copper cyanide compound based on 3-(5-(pyridin-4-yl)-1H-1,2,4-triazol-3-yl)pyridine via the transformation of acetonitrile to inorganic cyanide

Linyan Yang
, Liangliang Xin
, Jinlei Tian
, Peiyao Du
, Xiaohua Wei
, Shengyun Liao
, Yanping Zhang
, Rui Lv
, Wen Gu
, Xin Liu

Nankai University
Tianjin University
Tianjin Key Laboratory of Metal and Molecule Based Material Chemistry

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

One-pot solvothermal treatments of acetonitrile, water, LiOH, Cu(CH ₃COO)₂·H₂O and 3-(5-(pyridin-4-yl)-1H-1, 2,4-triazol-3-yl)pyridine (HL) yielded a rare copper cyanide coordination polymer, [Cu₂(L) (CN)]_n (1). The existence of a cyanide group in compound 1 may be due to the decomposition of acetonitrile at the relatively high temperature (160 C) and autogenous pressure of the reaction. Compound 1 has been characterized by single-crystal X-ray diffraction, XRPD, IR, and elemental analysis. Compound 1 is a 3D copper cyanide coordination polymer, and a ({6.8.10}2{6.83.102}) topology in 1 is created. In addition, the optical and catalytic properties have been investigated.

Original language	English
Pages (from-to)	1-5
Number of pages	5
Journal	Journal of Molecular Structure
Volume	1064
Issue number	1
DOIs	https://doi.org/10.1016/j.molstruc.2014.01.090
State	Published - 5 May 2014
Externally published	Yes

Keywords

Catalysis
Copper cyanide compound
Luminescent

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10.1016/j.molstruc.2014.01.090

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@article{37d338798c2247c0a5492f449366f054,

title = "Synthesis of a rare 3D copper cyanide compound based on 3-(5-(pyridin-4-yl)-1H-1,2,4-triazol-3-yl)pyridine via the transformation of acetonitrile to inorganic cyanide",

abstract = "One-pot solvothermal treatments of acetonitrile, water, LiOH, Cu(CH 3COO)2·H2O and 3-(5-(pyridin-4-yl)-1H-1, 2,4-triazol-3-yl)pyridine (HL) yielded a rare copper cyanide coordination polymer, [Cu2(L) (CN)]n (1). The existence of a cyanide group in compound 1 may be due to the decomposition of acetonitrile at the relatively high temperature (160 C) and autogenous pressure of the reaction. Compound 1 has been characterized by single-crystal X-ray diffraction, XRPD, IR, and elemental analysis. Compound 1 is a 3D copper cyanide coordination polymer, and a (\{6.8.10\}2\{6.83.102\}) topology in 1 is created. In addition, the optical and catalytic properties have been investigated.",

keywords = "Catalysis, Copper cyanide compound, Luminescent",

author = "Linyan Yang and Liangliang Xin and Jinlei Tian and Peiyao Du and Xiaohua Wei and Shengyun Liao and Yanping Zhang and Rui Lv and Wen Gu and Xin Liu",

year = "2014",

month = may,

day = "5",

doi = "10.1016/j.molstruc.2014.01.090",

language = "英语",

volume = "1064",

pages = "1--5",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier B.V.",

number = "1",

}

TY - JOUR

T1 - Synthesis of a rare 3D copper cyanide compound based on 3-(5-(pyridin-4-yl)-1H-1,2,4-triazol-3-yl)pyridine via the transformation of acetonitrile to inorganic cyanide

AU - Yang, Linyan

AU - Xin, Liangliang

AU - Tian, Jinlei

AU - Du, Peiyao

AU - Wei, Xiaohua

AU - Liao, Shengyun

AU - Zhang, Yanping

AU - Lv, Rui

AU - Gu, Wen

AU - Liu, Xin

PY - 2014/5/5

Y1 - 2014/5/5

N2 - One-pot solvothermal treatments of acetonitrile, water, LiOH, Cu(CH 3COO)2·H2O and 3-(5-(pyridin-4-yl)-1H-1, 2,4-triazol-3-yl)pyridine (HL) yielded a rare copper cyanide coordination polymer, [Cu2(L) (CN)]n (1). The existence of a cyanide group in compound 1 may be due to the decomposition of acetonitrile at the relatively high temperature (160 C) and autogenous pressure of the reaction. Compound 1 has been characterized by single-crystal X-ray diffraction, XRPD, IR, and elemental analysis. Compound 1 is a 3D copper cyanide coordination polymer, and a ({6.8.10}2{6.83.102}) topology in 1 is created. In addition, the optical and catalytic properties have been investigated.

AB - One-pot solvothermal treatments of acetonitrile, water, LiOH, Cu(CH 3COO)2·H2O and 3-(5-(pyridin-4-yl)-1H-1, 2,4-triazol-3-yl)pyridine (HL) yielded a rare copper cyanide coordination polymer, [Cu2(L) (CN)]n (1). The existence of a cyanide group in compound 1 may be due to the decomposition of acetonitrile at the relatively high temperature (160 C) and autogenous pressure of the reaction. Compound 1 has been characterized by single-crystal X-ray diffraction, XRPD, IR, and elemental analysis. Compound 1 is a 3D copper cyanide coordination polymer, and a ({6.8.10}2{6.83.102}) topology in 1 is created. In addition, the optical and catalytic properties have been investigated.

KW - Catalysis

KW - Copper cyanide compound

KW - Luminescent

UR - https://www.scopus.com/pages/publications/84894552072

U2 - 10.1016/j.molstruc.2014.01.090

DO - 10.1016/j.molstruc.2014.01.090

M3 - 文章

AN - SCOPUS:84894552072

SN - 0022-2860

VL - 1064

SP - 1

EP - 5

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 1

ER -

Synthesis of a rare 3D copper cyanide compound based on 3-(5-(pyridin-4-yl)-1H-1,2,4-triazol-3-yl)pyridine via the transformation of acetonitrile to inorganic cyanide

Abstract

Keywords

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