Synthesis, crystal structure and blue photoluminescence of a metal-organic framework constructed from triangular [Zn3(μ3-OH)] clusters with bis(tetrazole)amine ligands

Xiao Xia Tian; Shao Bo Qu; Wu Sen Zhang; Zhuo Xu

Synthesis, crystal structure and blue photoluminescence of a metal-organic framework constructed from triangular [Zn₃(μ₃-OH)] clusters with bis(tetrazole)amine ligands

Xiao Xia Tian
, Shao Bo Qu
, Wu Sen Zhang
, Zhuo Xu

Faculty of Electronic and Information Engineering

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

A new metal-organic framework, {Zn[Zn₃(BTA)₃(μ ₃-OH)(H₂O)₃]₂}_n 1, has been synthesized under hydrothermal reaction of ZnCI₂ and bis(5-tetrazolyl)amine (H₂BTA), and characterized by elemental analysis, FT-IR, Raman spectrum, X-ray single-crystal diffraction, TGA and photoluminescence measurements. Compound 1 crystallizes in the trigonal system, space group P-3cl, a = 13.667(3), c = 12.981(3) Å,V= 2099.6(8) Å₃ and Z = 2. The BTA^2- ligand in 1 assumes the μ₃ tetradentate mode with both 1,2- and 1,4-tetrazole bridges, generating an unusual 2-D layer, in which the [Zn₃(μ₃- OH)] triangular motifs act as three-connecting nodes and the mononuclear Zn atoms as six-connecting nodes that are inter-linked by organic ligands. Adjacent 2-D metal-organic layers are linked by strong hydrogen bonds to form a novel 3-D supramolecular framework. Complex 1 exhibits blue fluorescence emission in the solid state at ambient temperature.

Original language	English
Pages (from-to)	1053-1060
Number of pages	8
Journal	Jiegou Huaxue
Volume	28
Issue number	9
State	Published - 2009

Keywords

Bis(5-tetrazolyl)amine
Luminescence
Metal-organic framework
Topology
Triangular cluster

Cite this

@article{37ef4b02a7af45fd8bd1077f27e3e894,

title = "Synthesis, crystal structure and blue photoluminescence of a metal-organic framework constructed from triangular [Zn3(μ3-OH)] clusters with bis(tetrazole)amine ligands",

abstract = "A new metal-organic framework, \{Zn[Zn3(BTA)3(μ 3-OH)(H2O)3]2\}n 1, has been synthesized under hydrothermal reaction of ZnCI2 and bis(5-tetrazolyl)amine (H2BTA), and characterized by elemental analysis, FT-IR, Raman spectrum, X-ray single-crystal diffraction, TGA and photoluminescence measurements. Compound 1 crystallizes in the trigonal system, space group P-3cl, a = 13.667(3), c = 12.981(3) {\AA},V= 2099.6(8) {\AA}3 and Z = 2. The BTA2- ligand in 1 assumes the μ3 tetradentate mode with both 1,2- and 1,4-tetrazole bridges, generating an unusual 2-D layer, in which the [Zn3(μ3- OH)] triangular motifs act as three-connecting nodes and the mononuclear Zn atoms as six-connecting nodes that are inter-linked by organic ligands. Adjacent 2-D metal-organic layers are linked by strong hydrogen bonds to form a novel 3-D supramolecular framework. Complex 1 exhibits blue fluorescence emission in the solid state at ambient temperature.",

keywords = "Bis(5-tetrazolyl)amine, Luminescence, Metal-organic framework, Topology, Triangular cluster",

author = "Tian, \{Xiao Xia\} and Qu, \{Shao Bo\} and Zhang, \{Wu Sen\} and Zhuo Xu",

year = "2009",

language = "英语",

volume = "28",

pages = "1053--1060",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "9",

}

TY - JOUR

T1 - Synthesis, crystal structure and blue photoluminescence of a metal-organic framework constructed from triangular [Zn3(μ3-OH)] clusters with bis(tetrazole)amine ligands

AU - Tian, Xiao Xia

AU - Qu, Shao Bo

AU - Zhang, Wu Sen

AU - Xu, Zhuo

PY - 2009

Y1 - 2009

N2 - A new metal-organic framework, {Zn[Zn3(BTA)3(μ 3-OH)(H2O)3]2}n 1, has been synthesized under hydrothermal reaction of ZnCI2 and bis(5-tetrazolyl)amine (H2BTA), and characterized by elemental analysis, FT-IR, Raman spectrum, X-ray single-crystal diffraction, TGA and photoluminescence measurements. Compound 1 crystallizes in the trigonal system, space group P-3cl, a = 13.667(3), c = 12.981(3) Å,V= 2099.6(8) Å3 and Z = 2. The BTA2- ligand in 1 assumes the μ3 tetradentate mode with both 1,2- and 1,4-tetrazole bridges, generating an unusual 2-D layer, in which the [Zn3(μ3- OH)] triangular motifs act as three-connecting nodes and the mononuclear Zn atoms as six-connecting nodes that are inter-linked by organic ligands. Adjacent 2-D metal-organic layers are linked by strong hydrogen bonds to form a novel 3-D supramolecular framework. Complex 1 exhibits blue fluorescence emission in the solid state at ambient temperature.

AB - A new metal-organic framework, {Zn[Zn3(BTA)3(μ 3-OH)(H2O)3]2}n 1, has been synthesized under hydrothermal reaction of ZnCI2 and bis(5-tetrazolyl)amine (H2BTA), and characterized by elemental analysis, FT-IR, Raman spectrum, X-ray single-crystal diffraction, TGA and photoluminescence measurements. Compound 1 crystallizes in the trigonal system, space group P-3cl, a = 13.667(3), c = 12.981(3) Å,V= 2099.6(8) Å3 and Z = 2. The BTA2- ligand in 1 assumes the μ3 tetradentate mode with both 1,2- and 1,4-tetrazole bridges, generating an unusual 2-D layer, in which the [Zn3(μ3- OH)] triangular motifs act as three-connecting nodes and the mononuclear Zn atoms as six-connecting nodes that are inter-linked by organic ligands. Adjacent 2-D metal-organic layers are linked by strong hydrogen bonds to form a novel 3-D supramolecular framework. Complex 1 exhibits blue fluorescence emission in the solid state at ambient temperature.

KW - Bis(5-tetrazolyl)amine

KW - Luminescence

KW - Metal-organic framework

KW - Topology

KW - Triangular cluster

UR - https://www.scopus.com/pages/publications/70350331753

M3 - 文章

AN - SCOPUS:70350331753

SN - 0254-5861

VL - 28

SP - 1053

EP - 1060

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 9

ER -

Synthesis, crystal structure and blue photoluminescence of a metal-organic framework constructed from triangular [Zn₃(μ₃-OH)] clusters with bis(tetrazole)amine ligands

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