Synthesis and Structural Characterization of the Helical Coordination Polymers [Co(phen)(oba)(H2O)2] and [Cd3(phen) 3(oba)2(Hoba)2(H2O)2] phen = 1,10-phenanthroline; oba = 4,4′-oxybis(benzoate)

Yan Zhen Zheng; Gao Feng Liu; Bao Hui Ye; Xiao Ming Chen

doi:10.1002/zaac.200300297

Synthesis and Structural Characterization of the Helical Coordination Polymers [Co(phen)(oba)(H₂O)₂] and [Cd₃(phen) ₃(oba)₂(Hoba)₂(H₂O)₂] phen = 1,10-phenanthroline; oba = 4,4′-oxybis(benzoate)

Yan Zhen Zheng
, Gao Feng Liu
, Bao Hui Ye
, Xiao Ming Chen

Sun Yat-Sen University

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

Two coordination polymers, [Co(phen)(oba)(H₂O)₂] (1) and [Cd₃(phen)₃(oba)₂(Hoba)₂(H ₂O)₂] (2) (oba = 4,4′-oxybis-(benzoate), phen = 1,10-phenanthroline) have been synthesized under hydrothermal conditions. Complex 1 crystallizes in monoclinic, P2₁/n, a = 7.543(6), b = 33.05(2), c = 9.902(5) Å, β = 103.69(2)°, V = 2398(3) Å³, Z = 4; 2 in monoclinic, P2/n, a = 15.11(1), b = 10.069(8), c = 28.02(2) Å, β = 101.83(1)°, V = 4174(5) Å³, Z = 2. X-ray single-crystal diffraction investigations shows that the complexes 1 and 2 consist of helical chains, which are further assembled into layers and networks via supramolecular interactions such as π-π stacking interactions and hydrogen bonds, respectively. The results indicate that the coordination environment is one of the most important factors for assembly of single-stranded helical chains into double-stranded helical chains via supramolecular interactions.

Original language	English
Pages (from-to)	296-300
Number of pages	5
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	630
Issue number	2
DOIs	https://doi.org/10.1002/zaac.200300297
State	Published - Feb 2004
Externally published	Yes

Keywords

4,4′-Oxybis(benzoate)
Coordination polymers
Helicity
Supramolecular interaction

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10.1002/zaac.200300297

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@article{e1eada841ea74d159dd8f13245d1b812,

title = "Synthesis and Structural Characterization of the Helical Coordination Polymers [Co(phen)(oba)(H2O)2] and [Cd3(phen) 3(oba)2(Hoba)2(H2O)2] phen = 1,10-phenanthroline; oba = 4,4′-oxybis(benzoate)",

abstract = "Two coordination polymers, [Co(phen)(oba)(H2O)2] (1) and [Cd3(phen)3(oba)2(Hoba)2(H 2O)2] (2) (oba = 4,4′-oxybis-(benzoate), phen = 1,10-phenanthroline) have been synthesized under hydrothermal conditions. Complex 1 crystallizes in monoclinic, P21/n, a = 7.543(6), b = 33.05(2), c = 9.902(5) {\AA}, β = 103.69(2)°, V = 2398(3) {\AA}3, Z = 4; 2 in monoclinic, P2/n, a = 15.11(1), b = 10.069(8), c = 28.02(2) {\AA}, β = 101.83(1)°, V = 4174(5) {\AA}3, Z = 2. X-ray single-crystal diffraction investigations shows that the complexes 1 and 2 consist of helical chains, which are further assembled into layers and networks via supramolecular interactions such as π-π stacking interactions and hydrogen bonds, respectively. The results indicate that the coordination environment is one of the most important factors for assembly of single-stranded helical chains into double-stranded helical chains via supramolecular interactions.",

keywords = "4,4′-Oxybis(benzoate), Coordination polymers, Helicity, Supramolecular interaction",

author = "Zheng, \{Yan Zhen\} and Liu, \{Gao Feng\} and Ye, \{Bao Hui\} and Chen, \{Xiao Ming\}",

year = "2004",

month = feb,

doi = "10.1002/zaac.200300297",

language = "英语",

volume = "630",

pages = "296--300",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "2",

}

Synthesis and Structural Characterization of the Helical Coordination Polymers [Co(phen)(oba)(H₂O)₂] and [Cd₃(phen) ₃(oba)₂(Hoba)₂(H₂O)₂] phen = 1,10-phenanthroline; oba = 4,4′-oxybis(benzoate). / Zheng, Yan Zhen; Liu, Gao Feng; Ye, Bao Hui et al.
In: Zeitschrift fur Anorganische und Allgemeine Chemie, Vol. 630, No. 2, 02.2004, p. 296-300.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and Structural Characterization of the Helical Coordination Polymers [Co(phen)(oba)(H2O)2] and [Cd3(phen) 3(oba)2(Hoba)2(H2O)2] phen = 1,10-phenanthroline; oba = 4,4′-oxybis(benzoate)

AU - Zheng, Yan Zhen

AU - Liu, Gao Feng

AU - Ye, Bao Hui

AU - Chen, Xiao Ming

PY - 2004/2

Y1 - 2004/2

N2 - Two coordination polymers, [Co(phen)(oba)(H2O)2] (1) and [Cd3(phen)3(oba)2(Hoba)2(H 2O)2] (2) (oba = 4,4′-oxybis-(benzoate), phen = 1,10-phenanthroline) have been synthesized under hydrothermal conditions. Complex 1 crystallizes in monoclinic, P21/n, a = 7.543(6), b = 33.05(2), c = 9.902(5) Å, β = 103.69(2)°, V = 2398(3) Å3, Z = 4; 2 in monoclinic, P2/n, a = 15.11(1), b = 10.069(8), c = 28.02(2) Å, β = 101.83(1)°, V = 4174(5) Å3, Z = 2. X-ray single-crystal diffraction investigations shows that the complexes 1 and 2 consist of helical chains, which are further assembled into layers and networks via supramolecular interactions such as π-π stacking interactions and hydrogen bonds, respectively. The results indicate that the coordination environment is one of the most important factors for assembly of single-stranded helical chains into double-stranded helical chains via supramolecular interactions.

AB - Two coordination polymers, [Co(phen)(oba)(H2O)2] (1) and [Cd3(phen)3(oba)2(Hoba)2(H 2O)2] (2) (oba = 4,4′-oxybis-(benzoate), phen = 1,10-phenanthroline) have been synthesized under hydrothermal conditions. Complex 1 crystallizes in monoclinic, P21/n, a = 7.543(6), b = 33.05(2), c = 9.902(5) Å, β = 103.69(2)°, V = 2398(3) Å3, Z = 4; 2 in monoclinic, P2/n, a = 15.11(1), b = 10.069(8), c = 28.02(2) Å, β = 101.83(1)°, V = 4174(5) Å3, Z = 2. X-ray single-crystal diffraction investigations shows that the complexes 1 and 2 consist of helical chains, which are further assembled into layers and networks via supramolecular interactions such as π-π stacking interactions and hydrogen bonds, respectively. The results indicate that the coordination environment is one of the most important factors for assembly of single-stranded helical chains into double-stranded helical chains via supramolecular interactions.

KW - 4,4′-Oxybis(benzoate)

KW - Coordination polymers

KW - Helicity

KW - Supramolecular interaction

UR - https://www.scopus.com/pages/publications/1242329282

U2 - 10.1002/zaac.200300297

DO - 10.1002/zaac.200300297

M3 - 文章

AN - SCOPUS:1242329282

SN - 0044-2313

VL - 630

SP - 296

EP - 300

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 2

ER -

Synthesis and Structural Characterization of the Helical Coordination Polymers [Co(phen)(oba)(H₂O)₂] and [Cd₃(phen) ₃(oba)₂(Hoba)₂(H₂O)₂] phen = 1,10-phenanthroline; oba = 4,4′-oxybis(benzoate)

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