TY - JOUR
T1 - Synthesis and crystal structure of a two-hydroxyphenyl adamantane-Type epoxy resin
AU - Wang, Shu Juan
AU - Jing, Xin Li
AU - Meng, Yun Dong
AU - Jia, Qin Xiang
PY - 2017/3/15
Y1 - 2017/3/15
N2 - A two-hydroxyphenyl adamantane-Type epoxy resin oligomer, namely 1,3-bis(4- (2,3-epoxpropyloxy)phenyl) adamantine (BEPAD), has been synthesized and structurally characterized by single-crystal X-ray diffraction. The unit cell of C28H32O4: Mr = 432.5, monoclinic, space group P21/n, with a = 10.510(6), b = 16.972(9), c = 13.374(7) Å, β = 109.356(6)o, V = 2251(2) Å3, Z = 4, Dc = 1.277 Mgm-3 and μ(MoKα) = 0.084 mm-1. In BEPAD, the methylene and epoxide rings on two ends are statistically disordered. The intermolecular interactions are also discussed, suggesting that the intermolecular interactions in BEPAD are stronger than that in the crystals of similar compounds due to the large adamantine group between the two benzene rings.
AB - A two-hydroxyphenyl adamantane-Type epoxy resin oligomer, namely 1,3-bis(4- (2,3-epoxpropyloxy)phenyl) adamantine (BEPAD), has been synthesized and structurally characterized by single-crystal X-ray diffraction. The unit cell of C28H32O4: Mr = 432.5, monoclinic, space group P21/n, with a = 10.510(6), b = 16.972(9), c = 13.374(7) Å, β = 109.356(6)o, V = 2251(2) Å3, Z = 4, Dc = 1.277 Mgm-3 and μ(MoKα) = 0.084 mm-1. In BEPAD, the methylene and epoxide rings on two ends are statistically disordered. The intermolecular interactions are also discussed, suggesting that the intermolecular interactions in BEPAD are stronger than that in the crystals of similar compounds due to the large adamantine group between the two benzene rings.
KW - 1,3-bis(4-(2,3-epoxpropyloxy)phenyl) adamantine
KW - Crystal structure
KW - Epoxy resin
KW - Intermolecular interactions
UR - https://www.scopus.com/pages/publications/85016961590
U2 - 10.14102/j.cnki.0254-5861.2011-1078
DO - 10.14102/j.cnki.0254-5861.2011-1078
M3 - 文章
AN - SCOPUS:85016961590
SN - 0254-5861
VL - 36
SP - 396
EP - 400
JO - Jiegou Huaxue
JF - Jiegou Huaxue
IS - 3
ER -