TY - JOUR
T1 - Synthesis and crystal structure of 2,2'-(1,4-butanediyl)bis-(1H- benzoimidazole) Cd(II) complex
AU - Giro, Y. N.
AU - Wang, Y.
AU - Jiang, L.
AU - Feng, G. D.
AU - Zhao, W. X.
PY - 2011
Y1 - 2011
N2 - A novel Cd(II)complex (1) with 2,2'-(l,4-butanediyl)bis(lH-benzimidazole) (H2C4BIm) has been synthesized and characterized by X-ray single-crystal diffraction analysis. The complex crystallizes in monoclinic, space group P21/C with a = 7.003(5) Å, b = 18.111(5) Å, c = 16.566(5) Å, V = 2099.4(17) Å3, Z = 4, C 21H24N4O6Cd, Mr = 540.84, Dc = 1.711 g cm-3, F(000) = 1096, μ = 1.088 mm-1, the final R = 0.0367 and wR = 0.0622 for 3367 observed reflections with I > 2σ(I). The coordination geometry of Cd(II) atom is 5-coordinated to form trigonal bipyramidal geometry. The crystal structure is represented by continuous zigzag chains of C21H24N4O6Cd molecules, these continuous zigzag chains are further linked by intermolecular hydrogen bondings and C-H-:π interaction into a 3-dimensional framework.
AB - A novel Cd(II)complex (1) with 2,2'-(l,4-butanediyl)bis(lH-benzimidazole) (H2C4BIm) has been synthesized and characterized by X-ray single-crystal diffraction analysis. The complex crystallizes in monoclinic, space group P21/C with a = 7.003(5) Å, b = 18.111(5) Å, c = 16.566(5) Å, V = 2099.4(17) Å3, Z = 4, C 21H24N4O6Cd, Mr = 540.84, Dc = 1.711 g cm-3, F(000) = 1096, μ = 1.088 mm-1, the final R = 0.0367 and wR = 0.0622 for 3367 observed reflections with I > 2σ(I). The coordination geometry of Cd(II) atom is 5-coordinated to form trigonal bipyramidal geometry. The crystal structure is represented by continuous zigzag chains of C21H24N4O6Cd molecules, these continuous zigzag chains are further linked by intermolecular hydrogen bondings and C-H-:π interaction into a 3-dimensional framework.
KW - Crystal structure
KW - Hydrothermal synthesis
KW - Synthesis
UR - https://www.scopus.com/pages/publications/79958038807
M3 - 文章
AN - SCOPUS:79958038807
SN - 0970-7077
VL - 23
SP - 3647
EP - 3650
JO - Asian Journal of Chemistry
JF - Asian Journal of Chemistry
IS - 8
ER -