Synthesis and characterization of poly(pyrrolyl methine)

Wei Yan; An Kuo Li; Chain Shu Hsu; Zhi Cheng Zhang; Mei Xiang Wan

Synthesis and characterization of poly(pyrrolyl methine)

Wei Yan
, An Kuo Li
, Chain Shu Hsu
, Zhi Cheng Zhang
, Mei Xiang Wan

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

A novel small band-gap conjugated polymer - poly[(3-acetylpyrrole-2,5-diyl)(4-dimethylaminobenzyliene)(3- acetylpyrrolequinodimethane-2,5-diyl)] (PAPDMABE) - and its precursor were synthesized by a simple method and characterized by ¹H-NMR, FT-IR, TGA and UV-VIS. The polymer can be dissolved in strong polar solvents such as DMSO, DMF or NMP. The band-gap energy of PAPDMABE was found to be 0.95 eV. The conductivity of doped products with iodine falls in the range of a semiconductor.

Original language	English
Pages (from-to)	499-502
Number of pages	4
Journal	Chinese Journal of Polymer Science (English Edition)
Volume	19
Issue number	5
State	Published - Sep 2001

Keywords

Conducting polymer
Poly(pyrrolyl methine)
Small band-gap

Cite this

@article{19ee3ca26fe1426f94e66052b66b21d4,

title = "Synthesis and characterization of poly(pyrrolyl methine)",

abstract = "A novel small band-gap conjugated polymer - poly[(3-acetylpyrrole-2,5-diyl)(4-dimethylaminobenzyliene)(3- acetylpyrrolequinodimethane-2,5-diyl)] (PAPDMABE) - and its precursor were synthesized by a simple method and characterized by 1H-NMR, FT-IR, TGA and UV-VIS. The polymer can be dissolved in strong polar solvents such as DMSO, DMF or NMP. The band-gap energy of PAPDMABE was found to be 0.95 eV. The conductivity of doped products with iodine falls in the range of a semiconductor.",

keywords = "Conducting polymer, Poly(pyrrolyl methine), Small band-gap",

author = "Wei Yan and Li, \{An Kuo\} and Hsu, \{Chain Shu\} and Zhang, \{Zhi Cheng\} and Wan, \{Mei Xiang\}",

year = "2001",

month = sep,

language = "英语",

volume = "19",

pages = "499--502",

journal = "Chinese Journal of Polymer Science (English Edition)",

issn = "0256-7679",

publisher = "Springer Verlag",

number = "5",

}

TY - JOUR

T1 - Synthesis and characterization of poly(pyrrolyl methine)

AU - Yan, Wei

AU - Li, An Kuo

AU - Hsu, Chain Shu

AU - Zhang, Zhi Cheng

AU - Wan, Mei Xiang

PY - 2001/9

Y1 - 2001/9

N2 - A novel small band-gap conjugated polymer - poly[(3-acetylpyrrole-2,5-diyl)(4-dimethylaminobenzyliene)(3- acetylpyrrolequinodimethane-2,5-diyl)] (PAPDMABE) - and its precursor were synthesized by a simple method and characterized by 1H-NMR, FT-IR, TGA and UV-VIS. The polymer can be dissolved in strong polar solvents such as DMSO, DMF or NMP. The band-gap energy of PAPDMABE was found to be 0.95 eV. The conductivity of doped products with iodine falls in the range of a semiconductor.

AB - A novel small band-gap conjugated polymer - poly[(3-acetylpyrrole-2,5-diyl)(4-dimethylaminobenzyliene)(3- acetylpyrrolequinodimethane-2,5-diyl)] (PAPDMABE) - and its precursor were synthesized by a simple method and characterized by 1H-NMR, FT-IR, TGA and UV-VIS. The polymer can be dissolved in strong polar solvents such as DMSO, DMF or NMP. The band-gap energy of PAPDMABE was found to be 0.95 eV. The conductivity of doped products with iodine falls in the range of a semiconductor.

KW - Conducting polymer

KW - Poly(pyrrolyl methine)

KW - Small band-gap

UR - https://www.scopus.com/pages/publications/0035599514

M3 - 文章

AN - SCOPUS:0035599514

SN - 0256-7679

VL - 19

SP - 499

EP - 502

JO - Chinese Journal of Polymer Science (English Edition)

JF - Chinese Journal of Polymer Science (English Edition)

IS - 5

ER -

Synthesis and characterization of poly(pyrrolyl methine)

Abstract

Keywords

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