Synthesis and characterization of germanium-centered three-dimensional crystalline porous aromatic framework

Ye Yuan; Jia Liu; Hao Ren; Xiaofei Jing; Wei Wang; Heping Ma; Fuxing Sun; Huijun Zhao

doi:10.1557/jmr.2011.433

Synthesis and characterization of germanium-centered three-dimensional crystalline porous aromatic framework

Ye Yuan
, Jia Liu
, Hao Ren
, Xiaofei Jing
, Wei Wang
, Heping Ma
, Fuxing Sun
, Huijun Zhao

School of Chemical Engineering and Technology

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Tetra(4-dihydroxyborylphenyl)germanium as the tetrahedral units and 1,2,4,5-tetrahydroxybenzene as linkers were selected to form a crystalline porous aromatic framework, CPAF-13, with the planar five-membered BO2C2 ring in its structure by a dehydration reaction. The crystallinity of CPAF-13 was confirmed by x-ray diffraction analysis. The Ar sorption measurement on activated CPAF-13 results in a surface area of 417 m ²/g, using Brunauer Emmett Teller model. CPAF-13 also shows a considerable adsorption capacity of H2.

Original language	English
Pages (from-to)	1417-1420
Number of pages	4
Journal	Journal of Materials Research
Volume	27
Issue number	10
DOIs	https://doi.org/10.1557/jmr.2011.433
State	Published - 28 May 2012

Keywords

Crystalline
Polymer
X-ray diffraction

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10.1557/jmr.2011.433

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title = "Synthesis and characterization of germanium-centered three-dimensional crystalline porous aromatic framework",

abstract = "Tetra(4-dihydroxyborylphenyl)germanium as the tetrahedral units and 1,2,4,5-tetrahydroxybenzene as linkers were selected to form a crystalline porous aromatic framework, CPAF-13, with the planar five-membered BO2C2 ring in its structure by a dehydration reaction. The crystallinity of CPAF-13 was confirmed by x-ray diffraction analysis. The Ar sorption measurement on activated CPAF-13 results in a surface area of 417 m 2/g, using Brunauer Emmett Teller model. CPAF-13 also shows a considerable adsorption capacity of H2.",

keywords = "Crystalline, Polymer, X-ray diffraction",

author = "Ye Yuan and Jia Liu and Hao Ren and Xiaofei Jing and Wei Wang and Heping Ma and Fuxing Sun and Huijun Zhao",

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doi = "10.1557/jmr.2011.433",

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T1 - Synthesis and characterization of germanium-centered three-dimensional crystalline porous aromatic framework

AU - Yuan, Ye

AU - Liu, Jia

AU - Ren, Hao

AU - Jing, Xiaofei

AU - Wang, Wei

AU - Ma, Heping

AU - Sun, Fuxing

AU - Zhao, Huijun

PY - 2012/5/28

Y1 - 2012/5/28

N2 - Tetra(4-dihydroxyborylphenyl)germanium as the tetrahedral units and 1,2,4,5-tetrahydroxybenzene as linkers were selected to form a crystalline porous aromatic framework, CPAF-13, with the planar five-membered BO2C2 ring in its structure by a dehydration reaction. The crystallinity of CPAF-13 was confirmed by x-ray diffraction analysis. The Ar sorption measurement on activated CPAF-13 results in a surface area of 417 m 2/g, using Brunauer Emmett Teller model. CPAF-13 also shows a considerable adsorption capacity of H2.

AB - Tetra(4-dihydroxyborylphenyl)germanium as the tetrahedral units and 1,2,4,5-tetrahydroxybenzene as linkers were selected to form a crystalline porous aromatic framework, CPAF-13, with the planar five-membered BO2C2 ring in its structure by a dehydration reaction. The crystallinity of CPAF-13 was confirmed by x-ray diffraction analysis. The Ar sorption measurement on activated CPAF-13 results in a surface area of 417 m 2/g, using Brunauer Emmett Teller model. CPAF-13 also shows a considerable adsorption capacity of H2.

KW - Crystalline

KW - Polymer

KW - X-ray diffraction

UR - https://www.scopus.com/pages/publications/84860815655

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DO - 10.1557/jmr.2011.433

M3 - 文章

AN - SCOPUS:84860815655

SN - 0884-2914

VL - 27

SP - 1417

EP - 1420

JO - Journal of Materials Research

JF - Journal of Materials Research

IS - 10

ER -

Synthesis and characterization of germanium-centered three-dimensional crystalline porous aromatic framework

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Keywords

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