Synthesis and characterization of corona-resistant nanocluster-trapped polyimide/silica composites

M. Y. Zhang; Chu Yan; Fan Yong; Q. Q. Lei

Synthesis and characterization of corona-resistant nanocluster-trapped polyimide/silica composites

M. Y. Zhang
, Chu Yan
, Fan Yong
, Q. Q. Lei

Harbin University of Science and Technology

Research output: Contribution to conference › Paper › peer-review

7 Scopus citations

Abstract

A new class of corona-resistant films made of nanocluster-trapped polyimide/silica composites that were synthesized by the sol-gel reaction was obtained by the hydrolysis and poly-condensation of tetraethoxysilane (TEOS) or methyl-triethoxysilane (MTEOS) in the solution of polyamic acid(PAA) dissolved in N,N-dimethylacetamide (DMAc), followed by heating. The chemical structure and the surface morphology of the composites films were characterized by Atomic Force Microscope (AFM) and Foruier Transform Infrared Spectroscope (FTIR). The corona-resistant capacity of the composites films was tested under high voltage using rod-plate electrode. The compatibility between the organic phase polyimide (PI) and inorganic phase silica (SiO₂) had great effects on the properties of PI/SiO₂ films, especially on their corona-resistant capacity. And this capacity of the Nanocluster-trapped PI/SiO₂ films increased with increased content of silica.

Original language	English
Pages	753-756
Number of pages	4
State	Published - 2003
Externally published	Yes
Event	Proceedings of the 7th International Conference on Properties and Applications of Dielectric Materials - Nagoya, Japan Duration: 1 Jun 2003 → 5 Jun 2003

Conference

Conference	Proceedings of the 7th International Conference on Properties and Applications of Dielectric Materials
Country/Territory	Japan
City	Nagoya
Period	1/06/03 → 5/06/03

Cite this

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title = "Synthesis and characterization of corona-resistant nanocluster-trapped polyimide/silica composites",

abstract = "A new class of corona-resistant films made of nanocluster-trapped polyimide/silica composites that were synthesized by the sol-gel reaction was obtained by the hydrolysis and poly-condensation of tetraethoxysilane (TEOS) or methyl-triethoxysilane (MTEOS) in the solution of polyamic acid(PAA) dissolved in N,N-dimethylacetamide (DMAc), followed by heating. The chemical structure and the surface morphology of the composites films were characterized by Atomic Force Microscope (AFM) and Foruier Transform Infrared Spectroscope (FTIR). The corona-resistant capacity of the composites films was tested under high voltage using rod-plate electrode. The compatibility between the organic phase polyimide (PI) and inorganic phase silica (SiO2) had great effects on the properties of PI/SiO2 films, especially on their corona-resistant capacity. And this capacity of the Nanocluster-trapped PI/SiO2 films increased with increased content of silica.",

author = "Zhang, \{M. Y.\} and Chu Yan and Fan Yong and Lei, \{Q. Q.\}",

year = "2003",

language = "英语",

pages = "753--756",

note = "Proceedings of the 7th International Conference on Properties and Applications of Dielectric Materials ; Conference date: 01-06-2003 Through 05-06-2003",

}

TY - CONF

T1 - Synthesis and characterization of corona-resistant nanocluster-trapped polyimide/silica composites

AU - Zhang, M. Y.

AU - Yan, Chu

AU - Yong, Fan

AU - Lei, Q. Q.

PY - 2003

Y1 - 2003

N2 - A new class of corona-resistant films made of nanocluster-trapped polyimide/silica composites that were synthesized by the sol-gel reaction was obtained by the hydrolysis and poly-condensation of tetraethoxysilane (TEOS) or methyl-triethoxysilane (MTEOS) in the solution of polyamic acid(PAA) dissolved in N,N-dimethylacetamide (DMAc), followed by heating. The chemical structure and the surface morphology of the composites films were characterized by Atomic Force Microscope (AFM) and Foruier Transform Infrared Spectroscope (FTIR). The corona-resistant capacity of the composites films was tested under high voltage using rod-plate electrode. The compatibility between the organic phase polyimide (PI) and inorganic phase silica (SiO2) had great effects on the properties of PI/SiO2 films, especially on their corona-resistant capacity. And this capacity of the Nanocluster-trapped PI/SiO2 films increased with increased content of silica.

AB - A new class of corona-resistant films made of nanocluster-trapped polyimide/silica composites that were synthesized by the sol-gel reaction was obtained by the hydrolysis and poly-condensation of tetraethoxysilane (TEOS) or methyl-triethoxysilane (MTEOS) in the solution of polyamic acid(PAA) dissolved in N,N-dimethylacetamide (DMAc), followed by heating. The chemical structure and the surface morphology of the composites films were characterized by Atomic Force Microscope (AFM) and Foruier Transform Infrared Spectroscope (FTIR). The corona-resistant capacity of the composites films was tested under high voltage using rod-plate electrode. The compatibility between the organic phase polyimide (PI) and inorganic phase silica (SiO2) had great effects on the properties of PI/SiO2 films, especially on their corona-resistant capacity. And this capacity of the Nanocluster-trapped PI/SiO2 films increased with increased content of silica.

UR - https://www.scopus.com/pages/publications/0141939452

M3 - 论文

AN - SCOPUS:0141939452

SP - 753

EP - 756

T2 - Proceedings of the 7th International Conference on Properties and Applications of Dielectric Materials

Y2 - 1 June 2003 through 5 June 2003

ER -

Synthesis and characterization of corona-resistant nanocluster-trapped polyimide/silica composites

Abstract

Conference

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